The complex intermixing morphology is critical for the performance of the nanostructured polymer:fullerene bulk heterojunction (BHJ) solar cells. Here, time resolved in situ grazing incidence X‐ray diffraction and grazing incidence small angle X‐ray scattering are used to track the structure formation of BHJ thin films formed from the donor polymer poly(2,5‐bis(3‐hexadecylthiophen‐2‐yl)thieno[3,2‐b]thiophene) with different fullerene derivative acceptors. The formation of stable bimolecular crystals through the intercalation of fullerene molecules between the side chains of polymer crystallites is investigated. Such systems exhibit more efficient exciton dissociation but lower photo‐conductance and faster decay of charges. On the basis of the experimental observations, intercalation obviously takes place before or with the formation of the crystalline polymer domains. It results in more stable structures whose volume remains constant upon further drying. Three distinct periods of drying are observed and the formation of unidimensional fullerene channels along the π‐stacking direction of polymer crystallites is confirmed.

We investigate the cosmological evolution of an interacting phantom energy model in which the phantom field interacts with the dark matter. We discuss the existence and stability of scaling solutions for two types of specific interactions. One is motivated by the conformal transformation in string theory and the other is motivated by analogy with dissipation. In the former case, there exist no scaling solutions. In the latter case, there exist stable scaling solutions, which may give a phenomenological solution of the coincidence problem. Furthermore, the universe either accelerates forever or ends with a singularity, which is determined by not only the model parameters but also the initial velocity of the phantom field.

No abstract

No abstract

The formation of magnetic correlations in CeNiSn has been studied by muon spin rotation and relaxation (@RI spectroscopy covering the temperature range from 250K to 33 mK. Mainly a single crystalline sample was used. At high temperatures ( 5 2 K) a behaviour similar to that of a spin fluctuator like UA12 is observed, meaning that over the whole temperature range the paramagnetic moments fluctuate extremely fast ( 3 3 * 1014 Hz). Below 1 K the material exhibits properties typical for a paramagnet moving towards magnetic order, but no transition into long-range order could be observed down to the lowest measured temperature. The dependences of muon spin relaxation rate and muon spin precession frequency on external field (applied parallel to the a-axis) are unusual and indicate the formation of extended spin correlations up to short-range order.