We extend our previous shell effect observation in gold nanowires at room temperature under ultra high vacuum to the other two noble metals: silver and copper. Similar to gold, silver nanowires present two series of exceptionally stable diameters related to electronic and atomic shell filling. This observation is in concordance to what was previously found for alkali metal nanowires. Copper however presents only electronic shell filling. Remarkably we find that shell structure survives under ambient conditions for gold and silver.
The formation of gold nanowires in vacuum at room temperature reveals a
periodic spectrum of exceptionally stable diameters. This is identified as
shell structure similar to that which was recently discovered for alkali metals
at low temperatures. The gold nanowires present two competing `magic' series of
stable diameters, one governed by electronic structure and the other by the
atomic packing.Comment: 4 pages, 4 figure
The mechanical properties of Pt monatomic chains were investigated by a simultaneous measurement of effective stiffness and conductance using our recently developed mechanically controllable break junction technique with a tuning fork as a force sensor. When stretching a monatomic contact ͑two-atom chain͒, the stiffness and conductance increases at the early stage of stretching and then decreases just before breaking, which is attributed to a transition of the chain configuration and bond weakening. A statistical analysis was made to investigate the mechanical properties of monatomic chains. The average stiffness shows minima at the peak positions of the length histogram. From this result, we conclude that the peaks in the length histogram are a measure of the number of atoms in the chains and that the chains break from a strained state. Additionally, we find that the smaller the initial stiffness of the chain is, the longer the chain becomes. This shows that softer chains can be stretched longer.
We report experiments on aluminium nanowires in ultra-high vacuum at room temperature that reveal a periodic spectrum of exceptionally stable structures. Two 'magic' series of stable structures are observed: at low conductance, the formation of stable nanowires is governed by electronic shell effects whereas for larger contacts atomic packing dominates. The crossover between the two regimes is found to be smooth. A detailed comparison of the experimental results to a theoretical stability analysis indicates that, while the main features of the observed electron-shell structure are similar to those of alkali and noble metals, a sequence of extremely stable wires plays a unique role in aluminium. This series appears isolated in conductance histograms and can be attributed to 'superdeformed' non-axisymmetric nanowires.
We have developed a sensor to study the mechanical stiffness of atomic-size contacts. It consists of a modification of the mechanically controllable break-junction technique, using a quartz tuning fork resonator as force sensor. We present first results of measurements of the force constants in gold atomic contacts. In the formation of chains of single-metal atoms, the folding in of individual atoms from the banks into the chain can be observed. This sensor allows one to measure forces in atomic contacts for a wide variety of metals, as illustrated with the first measurements on platinum.
Electrochemical methods have recently become an interesting tool for fabricating and characterizing nanostructures at room temperature. Simplicity, low cost and reversibility are some of the advantages of this technique that allows to work at the nanoscale without requiring sophisticated instrumentation. In our experimental setup, we measure the conductance across a nanocontact fabricated either by dissolving a macroscopic gold wire or by depositing gold in between two separated gold electrodes. We have achieved a high level of control on the electrochemical fabrication of atomic-sized contacts in gold. The use of electrochemistry as a reproducible technique to prepare nanocontacts will open several possibilities that are not feasible with other methodologies. It involves, also, the possibility of reproducing experiments that today are made by more expensive, complicated or irreversible methods. As example, we show here a comparison of the results when looking for shell effects in gold nanocontacts with those obtained by other techniques.
We have investigated the uncertainty sources that affect the traceability of dimensional measurements using the VIScan of the Zeiss F25 coordinate measuring machine (CMM). Our experimental results on line-width measurements are promising, having a repeatability below 120 nm and moreover they are reproducible for all light settings investigated. The comparison with the measurements performed on a facility used for line-scale calibrations provides very good agreement. At present we can report an uncertainty below 0.45 µm for line-width calibrations. This would be the first traceable F25 VIScan, and to our knowledge one of the first truly traceable vision systems for line-width calibrations.
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