Photothermal deflection spectroscopy was applied to the selective detection of iron(II) chelate with ferrozine by its sorption preconcentration on Silufol plates. The linearity range was 1 x 10(-11) - 6 x 10(-8) mol cm(-2) of chelate at the plate surface, which corresponded to 1 x 10(-9) -4 x 10(-6) M of chelate in solution. The limits of detection and quantification are 8 x 10(-12) and 2.5 x 10(-11) mol cm(-2) at the plate from 15 microL of test solution (0.5 nM and 1.5 nM in solution, respectively), and the absolute detection limit is 8 fmol in the whole spot applied to a plate. Characteristics and features of photothermal deflection detection are discussed.
Thermal lensing was used for the characterization of adsorption on laboratory glassware at a nanogram concentration level in solution. Sorption kinetics was studied, the sorption capacity of the glass for test substances was characterized, which was found to be several ng cm−2. Factors affecting adsorption were discussed. A procedure for handling laboratory glassware for eliminating sorption effects in determining nanogram amounts of iron in aqueous solutions was developed.
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