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Ultrafine particles, PM2.5 and PM10 mass concentration, NO(x), Ozone, SO2, back-trajectories of air masses and meteorological parameters were studied in a small city over the period February, 2013 to June, 2014. The profiles of PM2.5 and PM10 particles are provided, showing averaged values of 16.6 and 21.6 μg m(-3), respectively. The average number concentration of particles in the range of diameters 5.6-560 nm was 1.2 × 10(4)#/ cm(3) with contributions of 42, 51 and 7% from the nucleation, Aitken, and accumulation modes, respectively. The average number concentration of ultrafine particles was 1.1 × 10(4)#/ cm(3). The results obtained are evidence for some differences in the pollution of ambient air by particles in the studied town in comparison to bigger cities. Nucleation events due to emissions from the city were not observed, and traffic emissions amount to a small contribution to PM2.5 and PM10 particles which are mainly due to crustal origin from the arid surroundings and long-range transport from the Sahara Desert.

The purpose of this work is to contribute to the understanding of the photochemical air pollution in central-southern of the Iberian Peninsula, analysing the behaviour and variability of oxidant levels (OX = O(3) + NO(2)), measured in a polluted area with the highest concentration of heavy industry in central Spain. A detailed air pollution database was observed from two monitoring stations. The data period used was 2008 and 2009, around 210,000 data, selected for its pollution and meteorological statistics, which are very representative of the region. Data were collected every 15 min, however hourly values were used to analyse the seasonal and daily ozone, NO, NO(2) and OX cycles. The variation of OX concentrations with NO(x) is investigated, for the first time, in the centre of the Iberian Peninsula. The concentration of OX was calculated using the sum of a NO(x)-independent 'regional' contribution (i.e. the O(3) background), and a linearly NO(x)-dependent 'local' contribution. Monthly dependence of regional and local OX concentration was observed to determine when the maximum values may be expected. The variation of OX concentrations with levels of NO(x) was also measured, in order to pinpoint the atmospheric sources of OX in the polluted areas. The ratios [NO(2)]/[OX] and [NO(2)]/[NO(x)] vs. [NO(x)] were analysed to find the fraction of OX in the form of NO(2), and the possible source of the local NO(x)-dependent contribution, respectively. The progressive increase of the ratio [NO(2)]/[OX] with [NO(x)] observed shows a greater proportion of OX in the form of NO(2) as the level of NO( x ) increases. The higher measured values in the ratio [NO(2)]/[NO(x)] should not be attributed to NO(x) emissions by vehicles; they could be explained by industrial emission, termolecular reactions or formaldehyde and HONO directly emitted by vehicles exhausts. We also estimate the rate of NO(2) photolysis, J (NO(2)) = 0.18-0.64 min(-1), a key atmospheric reaction that influence O(3) production and then the regional air quality. The first surface plot study of annual variation of the daily mean oxidant levels, obtained for this polluted area may be used to improve the atmospheric photochemical dynamic in this region of the Iberian Peninsula where there are undeniable air quality problems.

Objetivo: describir los resultados derivados de realizar cirugía menor (CM) por el médico de Atención Primaria (AP) y analizar el acuerdo diagnóstico prequirúrgico-anatomopatológico. Diseño: estudio descriptivo, prospectivo. Participantes: intervenciones realizadas durante dos años por 2 médicos de AP.