An orifice flowmeter was used to measure the extensional viscosity of several non-pigmented fluids and paper coating colors containing calcium carbonate as pigment in the context of a jet coating application. The orifice flowmeter was first calibrated in terms of a dimensionless Euler number versus Reynolds number curve with Newtonian fluids. The calibration curve was then used to determine the apparent extensional viscosity of coating colors. In the strain rate range investigated, all the fluids were found to exhibit strain-thinning and the Trouton ratio of the coating colors was in the range 5 to 20. Jet coating tests were also carried out in order to evaluate the effect of the extensional viscosity on the jet performance. The extensional viscosity was shown to be a key parameter determining the configuration of the downstream meniscus in the web contact region.
Paper coating fluids also called colors are concentrated aqueous suspensions composed mainly of mineral pigments, thickeners, binders and dispersing agents. They are applied onto moving paper web for improving the optical and printing properties. Roll coating is one of the most used technologies for paper coating, however jet coating is currently a promising technology for high-speed processes. Coating colors are submitted to high strain rates in both roll or jet coaters, therefore the extensional viscosity plays a major role in the process. An orifice flowmeter was used for measuring the extensional properties of complex rheology fluids such as coating colors. The principle of this flowmeter is based on the relationship between pressure drop and the flow rate of fluid passing through a small orifice. The flowmeter was firstly calibrated in terms of a dimensionless Euler number as a function of the Reynolds number with Newtonian fluids. The calibration curve was then used to determine the apparent extensional viscosity of coating colors. Results of extensional properties of paper coating colors are presented and compared to shear viscosity. The ratio of extensional to shear viscosity (Trouton ratio) for some coating colors was shown to exceed considerably the theoretical value of 3 expected for Newtonian fluids.
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