Abstract:In the homologous series of p-chlorophenyl w-chloroalkyl sulphides (I), the first and second members reacted abnormally with amines to yield 1,w-bis(p-chlorophenylmercapto)allcanes (11). The fourth member of the series reacted 11ormally to produce 4-aminobutyl p-chlorophenyl sulphidc (111). The formation of I1 is explained on the basis of an alkyl-sulphur bond cleavage. The members of the p-chlorobenzyl series (VI) in general reacted with a~nines to form the cspected aminoalkyl sulphides (VII). However, the p-… Show more
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