“…An olefin Fe(CO) 4 complex was found to show CO wavenumbers at 2071, 2005, 1975 cm −1 . 106 The CO stretching frequencies of the germaborene Fe(CO) 4 complex 10 were observed at slightly lower wavenumbers 2051, 1983 and 1960 cm −1 indicating the germaborene as a slightly better donor ligand in comparison to the amino-9-fluorenylideneborane boraalkene and olefin ligand.…”
Germaborene chemistry is presented: halide substitution by carbon nucleophiles, Cp*Al insertion into the B–Br bond, cycloaddition of CO2, dimethylbutadiene and selenium and coordination of CuBr, AuCl and Fe(CO)4 fragments at the BGe double bond.
“…An olefin Fe(CO) 4 complex was found to show CO wavenumbers at 2071, 2005, 1975 cm −1 . 106 The CO stretching frequencies of the germaborene Fe(CO) 4 complex 10 were observed at slightly lower wavenumbers 2051, 1983 and 1960 cm −1 indicating the germaborene as a slightly better donor ligand in comparison to the amino-9-fluorenylideneborane boraalkene and olefin ligand.…”
Germaborene chemistry is presented: halide substitution by carbon nucleophiles, Cp*Al insertion into the B–Br bond, cycloaddition of CO2, dimethylbutadiene and selenium and coordination of CuBr, AuCl and Fe(CO)4 fragments at the BGe double bond.
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