Germaborene reactivity study – addition of carbon nucleophiles, cycloaddition reactions, coordination chemistry

Abstract

Germaborene chemistry is presented: halide substitution by carbon nucleophiles, Cp*Al insertion into the B–Br bond, cycloaddition of CO2, dimethylbutadiene and selenium and coordination of CuBr, AuCl and Fe(CO)4 fragments at the BGe double bond.