η3:η1⇌η2-tautomerism in carbonyliron complexes. Influence of substituents

Rybin, L. V.; Stelzer, N.A.; Garbusova, I.A.; Lokshin, B. V.; Rybinskaya, M. I.

doi:10.1016/0022-328x(84)80094-7

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From (1-oxabuta-13-diene)tetracarbonyliron(0) Complexes2

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2011

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Cited by 6 publications

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“…This factor has been attributed to the increased solvation of the open form in more polar solvents. The relationship between the ligand structure and the equilibrium position is more complex [33]. It was demonstrated that when the substituent at C-1 is bulky, the g 3 -allyl complexes 50 also predominate.…”

Section: From (1-oxabuta-13-diene)tetracarbonyliron(0) Complexesmentioning

confidence: 98%

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The chemistry of (1-azabuta-1,3-diene)tricarbonyliron(0) complexes

Danks

Wagner

2004

Journal of Organometallic Chemistry

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Section: From (1-oxabuta-13-diene)tetracarbonyliron(0) Complexesmentioning

confidence: 98%

“…When the reaction mixture is warmed, CO loss occurs and formation of the g 4 -complexes (53) is observed. This final step of the reaction has been demonstrated to proceed via the intermediacy of the 16-electron r-N-imine complexes (52) [30][31][32][33].…”

Section: From (1-oxabuta-13-diene)tetracarbonyliron(0) Complexesmentioning

confidence: 98%