δ-Gluconolactone in Organic Synthesis

Abstract

Rev. Virtual Quim. |Vol 3| |No. 4| |247-274| 247 Artigo δ-Gliconolactona em Síntese Orgânica Reis, M. I. P.; Mendes, M. T.; da Silva, F. C.; Ferreira, V. F.* Rev. Virtual Quim., 2011, 3 (4), 247-274. Data de publicação na Web: 11 de junho de 2011 Abstract: This review will address the importance and the applicability and describes some synthetic routes that use -gluconolactone (DGL) as a starting material for the preparation of other simple derivatives, carbohydrates, gluconamides, heterocycles, small chiral building block and in some total syntheses. ResumoNesta revisão serão abordadas a importância, aplicabilidade e algu as otas si téti as ue utiliza agliconolactona (DGL) como material de partida para a preparação de outros derivados simples, carboidratos, gliconamidas, heterociclos, pequenos blocos quirais e em algumas sínteses totais.

D‐Glucose, a Fascinating Biomolecule: History, Properties, Production and Application

“…Na área sintética é explorada como substrato, auxiliar e catalisador quiral. 73 Alguns derivados da Dglicose, tais como, o diacetonídeo da glicose ou simplesmente DAG, a gliconolactona (DGL) e o metilglicosídeo-acetal do benzaldeído são bem conhecidos dos químicos orgânicos, por serem comercialmente disponíveis ou facilmente preparados em laboratório. Convém destacar que são descritas várias outras pequenas rotas de transformação da Dglicose em substâncias quirais, aplicadas em síntese orgânica.…”

Glycolipid-Based Oleogels and Organogels: Promising Nanostructured Structuring Agents

“…In recent years, gluconolactone is one of the important value-added chemicals displaying broad applications in food, pharmaceutical, and construction industries. Current research work related to the various aspect of gluconolactone revealed its potential in drug delivery, 3D-printing, construction of stimuli-responsive biomaterials, chelating agent, expander, protein coagulant, acidifier, color, and preservative in the food industry. − It is worth mentioning that ricinoleic acid derivatives possesses a large spectrum of applications such as oral drug delivery, surface coating, cosmetics, and pharmaceuticals. , A broad range of applications displayed by gluconolactone and ricinoleic acid motivated us to select this as a starting material to design a structuring agent. In this study, we intended to synthesize a multifunctional structuring agent by judicious combination of gluconolactone and ricinoleic acid.…”