1956
DOI: 10.1002/zaac.19562870302
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Zur Kenntnis des Lithiumsulfids

Abstract: 1. Reines Lithiumsulfid wurde durch thermische Zersetzung von Lithiumhydrogensulfid bei 150°C erhalten. Das Lithiumhydrogensulfid wurde durch Umsetzen von Lithiumamylat mit Schwefelwasserstoff hergestellt. 2. Die Lösungsenthalpie von Lithiumsulfid in Wasser ist −15,3 kcal pro Mol. Die Neutralisationsenthalpie von einem Mol Schwefelwasserstoff mit 1 Mol Lithiumhydroxyd ist −6,7 kcal pro Mol H2S, mit 2 Mol Lithiumhydroxyd −6,9 kcal pro Mol H2S. 3. Die Bildungsenthalpie von Lithiumsulfid aus den Elementen ist −10… Show more

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Cited by 16 publications
(2 citation statements)
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“…Since, in general, ethanol was not used for dehydration for the reasons given above, its reducing action in respect to osmium tetroxide was also lacking. Ammonium sulfide was chosen instead, since hydrogen sulfide (as present in ammonium sulfide solution) is known to precipitate osmium oxysulfides from osmium tetroxide solution at an acid (10) or neutral (6) pH. Contrary to expectations, this treatment did not alter appreciably the cutting properties of the tissue, but it did change its appearance, as described earlier in this report.…”
Section: Methods Designed To Improve the Cutting Properties Of Embeddings--certainmentioning
confidence: 90%
“…Since, in general, ethanol was not used for dehydration for the reasons given above, its reducing action in respect to osmium tetroxide was also lacking. Ammonium sulfide was chosen instead, since hydrogen sulfide (as present in ammonium sulfide solution) is known to precipitate osmium oxysulfides from osmium tetroxide solution at an acid (10) or neutral (6) pH. Contrary to expectations, this treatment did not alter appreciably the cutting properties of the tissue, but it did change its appearance, as described earlier in this report.…”
Section: Methods Designed To Improve the Cutting Properties Of Embeddings--certainmentioning
confidence: 90%
“…The heat of formation, AH~98, for Li2S was obtained from the literature. It is reported to be -107, 400 -+ 200 cal by Juza and Uphoff (18). Assuming $2,8 of Cu2S $2,8 of Li~S…”
Section: Appendix Cmentioning
confidence: 93%