Zur Kenntnis der Iso‐ und Heteropolysäuren. XV. Mitteilung. Kritische Untersuchungen über die Konstitution der Heteropolysäuren

Present General Status of Understanding of Heteropoly Electrolytes and a Tracing of Some Major Highlights in the History of Their Elucidation

“…By 1908 approximately 750 heteropoly compounds had been reported and analyzed by over 250 authors, among the most active of whom were P. Chrétien, H. Copaux, H. von Euler-Chelpin, C. Friedheim, W. Gibbs, R. D. Hall, E. Marckwald, O. Pufahl, A. Rosenheim, E. F. Smith, and H. Struve. Rosenheim and Jaenicki 60b reviewed this early work.…”

H8[PV5Mo7O40] – A Unique Polyoxometalate for Acid and RedOx Catalysis: Synthesis, Characterization, and Modern Applications in Green Chemical Processes

“…He described the possibility that single cores of multicore anions are linked with each other by oxygen atoms [3] . These were later called “heteropolyacids” or “heteropolysalts” by Rosenheim and Jaenicke [4] …”

Polyoxomolybdates as Green Catalysts for Aerobic Oxidation

“…He described the yellow precipitate (ammonium 12-molybdophosphate) that is produced when ammonium molybdate is added in excess to phosphoric acid [17]. After the discovery of this first POM, the field of POM chemistry progressed significantly [18][19][20][21][22][23][24][25][26][27] and various types of structures were discovered. After that, an extensive literature on their synthesis and structure has been accumulated and summarized in the form of reviews as well as books.…”