Zinc-based triazole metal complexes for efficient iodine adsorption in water

A chemically robust amine-grafted Zn(ii)-based smart supramolecular gel as a regenerative platform for trace discrimination of nitro-antibiotics and assorted environmental toxins

“…The PXRD pattern of ZnXero is also in good agreement with those of similar Zn-triazole systems reported in the literature. 33,34 Mass spectral data expressed that the coordination ratio is 2 : 3 (Zn 2+ : DAT) for the gel and suggested that a dimeric Zn 2+ unit bridged by three triazole rings forms the core structure of the gel, along with three acetate counter ions i.e. one bridging and two terminal acetates.…”

Preparation and performance of PVC long‐term heat stabilizer based on the synergistic effect of uracil and metal complexes

“…The main difference was that the 3204 cm À1 peak almost vanishes in the infrared spectrum of [Zn(ttr)(OAc)], which was attributed to the tensile vibration peak of N-H, indicating that the amitrol deprotonation reaction did occur and thus confirming the coordination reaction. [18] Figure 2 presents the SEM image of [Zn(ttr)(OAc)]. [Zn(ttr)(OAc)] was a layered particle with a diameter of no more than 500 nm.…”

Construction of naphthalene diimide-based cadmium complexes and their application in iodine adsorption, photochromism, and photocatalysis

“…As adsorbent materials, metal–organic framework complexes have the advantages of high porosity, large specific surface area, controllable structure, high stability, and non-toxicity, showing a good adsorption capacity. 40–48…”

“…As adsorbent materials, metal-organic framework complexes have the advantages of high porosity, large specific surface area, controllable structure, high stability, and non-toxicity, showing a good adsorption capacity. [40][41][42][43][44][45][46][47][48] At present, there are many studies on naphthalimide (NDI) group complexes. [49][50][51][52][53][54] These complexes often have the advantages of the π-deficiency properties and give the π group (π⋯π stacking, anionic⋯π interaction, and CO⋯π interactions), forming a framework with less conventional weak noncovalent supramolecular interactions.…”