ZIF-67@Cellulose nanofiber hybrid membrane with controlled porosity for use as Li-ion battery separator

Sun, Xiuxuan; Xu, Wangwang; Zhang, Xiuqiang; Lei, Tingzhou; Lee, Sun-Young; Wu, Qinglin

doi:10.1016/j.jechem.2020.04.057

Cited by 112 publications

(40 citation statements)

References 41 publications

(47 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Sun et al also reported a ZIF-67/cellulose gel electroltye for LIBs, which exhibits satisfied electrochemical performance. [28] Similar strategy also is suitable to other batteries, such as sodium ion batteries. [29] However, in fact, it is difficult to obtain uniform composite membrane materials by simple physical blending of cellulose and inorganic fillers including MOFs.…”

Section: Combined With Liquid Electrolytesmentioning

confidence: 99%

Cellulose‐Based Electrolytes for Advanced Lithium‐Ion Batteries: Recent Advances and Future Perspectives

Zhang

Gao

Jin³

et al. 2022

ChemNanoMat

View full text Add to dashboard Cite

In the coming decades, it is urgent to find a way to power the future while keeping a clean environment and strong economic growth. Thus, it is expected to transition from using fossil fuels to renewable energy. Materials based on cellulose are abundant, low cost, sustainable, possess a high surface area, good thermal stability, biocompatibility, mechanical flexibility, and inherit unique layered fiber structure from cellulose, which can act as an ideal electrolyte matrix for sustainable and high energy density lithium‐ion batteries (LIBs). In this review, we focus on energy storage application of different forms of cellulose‐based electrolytes in LIBs. Specifically, we summarize the recent advances of cellulose‐based gel and solid‐state electrolytes, focusing on the gel electrolytes based on different types of plasticizers (cellulose‐based electrolytes for flexible LIBs also are introduced). Finally, several perspectives related to the cellulose‐based‐electrolytes for LIBs are proposed based on recent progress and our own evaluation.

show abstract

Section: Combined With Liquid Electrolytesmentioning

confidence: 99%

Cellulose‐Based Electrolytes for Advanced Lithium‐Ion Batteries: Recent Advances and Future Perspectives

Zhang

Gao

Jin³

et al. 2022

ChemNanoMat

View full text Add to dashboard Cite

show abstract

“…ZIF-67 is a conventional MOF made from binding the cobalt ion and 2-methylimidazole ligand. Due to its attractive structure, large surface area, distinct morphology, permanent nanoscale porosity and excellent chemical stability, it is widely used in various fields such as separation [33], adsorption [34], inhomogeneous decomposition [35], oxygen evolution [36] and electrochemical reaction [37].…”

Section: Mixingmentioning

confidence: 99%

Ternary metal-organic framework/multi-walled carbon nanotube/iron oxide nanocomposite for removal of butachlor pesticide

2022

View full text Add to dashboard Cite

Background Butachlor (BUT) as an organochlorine pesticide (OCP) that prevents weeds from growing has been used in the agriculture field. It remains in the environment for a long time and causes mutagenicity and cancer. Results In the current study, magnetic multi-walled carbon nanotube with zeolitic imidazolate frameworks-67 (Fe3O4–MWCNT–ZIF67) was used as adsorbent to remove BUT from the aqueous solution. The characteristics and the chemical composition of the adsorbent were evaluated using FE-SEM, TEM, MAP, EDX, FTIR, BET, TGA and VSM. The response surface methodology (RSM) as a method for the design of experiment was applied to optimize variables such as the initial concentration of BUT, adsorbent dosage, contact time and temperature in the batch experiment by central composite design (CCD). The optimum adsorption condition predicted by RSM was pH = 4.5, initial concentration = 5.75 ppm, dosage = 0.07 g and contact time = 95 min. The results showed that maximum removal efficiency for the butachlor is 86%. Conclusions Different adsorption isotherms were evaluated using adsorption equilibrium data and results showed that Temkin model has the best compatibility with the experimental data. In addition, the adsorption kinetics data were closer with pseudo-second-order model. Thermodynamic study showed that the adsorption process was spontaneous, endothermic and physical. This composite can be effectively used for the remediation/clean-up of groundwater and agricultural run-off water which are contaminated with harmful pesticides. Graphical Abstract

show abstract

“…This strategy shows exceptional electrolyte wettability and rate capability as shown in Figure 8b [231]. Other works in this field include composites based on bacterial cellulose nanocrystals (BCNCs) with polyether block amide (PEBAX) [232], zeolitic imidazolate framework-67 (ZIF-67) on the surface of cellulose nanofibers (CNFs) [233], poly(vinylidene fluoridehexafluoropropylene)/cellulose/carboxylic titanium dioxide (PVDF-HFP/cellulose/C-TiO2) composites [234], aramid nanofiber (ANF)/bacterial cellulose (BC) [200], cellulose nanofibrils (CNFs) reinforced pure cellulose paper (CCP) [235], and Lyocell fibrillated fibers [236], all showing exceptional electrochemical performance and rate capability (Figure 8c for ANF/BC separator). A novel PVDF/triphenyl phosphate (TPP)/cellulose acetate (CA) separator membrane was fabricated by electrospinning, and this membrane shows high porosity, improved thermal stability, superior electrolyte wettability, improved flame resistance, excellent electrochemical properties, and cycle stability when compared to the commercial separators (Figure 8d) [237].…”

Section: Separator Membranementioning

confidence: 99%

Recent Advances on Materials for Lithium-Ion Batteries

et al. 2021

View full text Add to dashboard Cite

Environmental issues related to energy consumption are mainly associated with the strong dependence on fossil fuels. To solve these issues, renewable energy sources systems have been developed as well as advanced energy storage systems. Batteries are the main storage system related to mobility, and they are applied in devices such as laptops, cell phones, and electric vehicles. Lithium-ion batteries (LIBs) are the most used battery system based on their high specific capacity, long cycle life, and no memory effects. This rapidly evolving field urges for a systematic comparative compilation of the most recent developments on battery technology in order to keep up with the growing number of materials, strategies, and battery performance data, allowing the design of future developments in the field. Thus, this review focuses on the different materials recently developed for the different battery components—anode, cathode, and separator/electrolyte—in order to further improve LIB systems. Moreover, solid polymer electrolytes (SPE) for LIBs are also highlighted. Together with the study of new advanced materials, materials modification by doping or synthesis, the combination of different materials, fillers addition, size manipulation, or the use of high ionic conductor materials are also presented as effective methods to enhance the electrochemical properties of LIBs. Finally, it is also shown that the development of advanced materials is not only focused on improving efficiency but also on the application of more environmentally friendly materials.

show abstract

ZIF-67@Cellulose nanofiber hybrid membrane with controlled porosity for use as Li-ion battery separator

Cited by 112 publications

References 41 publications

Cellulose‐Based Electrolytes for Advanced Lithium‐Ion Batteries: Recent Advances and Future Perspectives

Cellulose‐Based Electrolytes for Advanced Lithium‐Ion Batteries: Recent Advances and Future Perspectives

Ternary metal-organic framework/multi-walled carbon nanotube/iron oxide nanocomposite for removal of butachlor pesticide

Recent Advances on Materials for Lithium-Ion Batteries

Contact Info

Product

Resources

About