Through systematic
molecular dynamics simulations we theoretically investigate the potential
applications of hexagonal boron nitride (h-BN) for seawater desalination.
Our results indicate that the rationally designed h-BN membranes have
great permeability, selectivity, and controllability for water desalination.
The size and chemistry of the pores are shown to play an important
role in regulating the water flux and salt rejection. Pores with only
nitrogen atoms on the edges have higher fluxes than the boron-lined
pores. In particular, two-dimensional h-BN with medium-sized N4 pores
show 100% salt rejection with outstanding water permeability, which
is several orders of magnitude higher than that of conventional reverse
osmosis membranes. Furthermore, we study the mechanical strain effect
on the desalination performance of monolayer h-BN with relatively
small N3 pores, suggesting that water flux and salt rejection can
be precisely tuned by tensile strain. The findings in the present
work unambiguously propose that porous boron nitride nanosheets are
quite promising as new functional membranes for water desalination.
free information in English and Mandarin on the novel coronavirus COVID-19. The COVID-19 resource centre is hosted on Elsevier Connect, the company's public news and information website.Elsevier hereby grants permission to make all its COVID-19-related research that is available on the COVID-19 resource centre -including this research content -immediately available in PubMed Central and other publicly funded repositories, such as the WHO COVID database with rights for unrestricted research re-use and analyses in any form or by any means with acknowledgement of the original source. These permissions are granted for free by Elsevier for as long as the COVID-19 resource centre remains active.
Recent studies of the high energy‐conversion efficiency of the nanofluidic platform have revealed the enormous potential for efficient exploitation of electrokinetic phenomena in nanoporous membranes for clean‐energy harvesting from salinity gradients. Here, nanofluidic reverse electrodialysis (NF‐RED) consisting of vertically aligned boron‐nitride‐nanopore (VA‐BNNP) membranes is presented, which can efficiently harness osmotic power. The power density of the VA‐BNNP reaches up to 105 W m−2, which is several orders of magnitude higher than in other nanopores with similar pore sizes, leading to 165 mW m−2 of net power density (i.e., power per membrane area). Low‐pressure chemical vapor deposition technology is employed to uniformly deposit a thin BN layer within 1D anodized alumina pores to prepare a macroscopic VA‐BNNP membrane with a high nanopore density, ≈108 pores cm−2. These membranes can resolve fundamental questions regarding the ion mobility, liquid transport, and power generation in highly charged nanopores. It is shown that the transference number in the VA‐BNNP is almost constant over the entire salt concentration range, which is different from other nanopore systems. Moreover, it is also demonstrated that the BN deposition on the nanopore channels can significantly enhance the diffusio‐osmosis velocity by two orders of magnitude at a high salinity gradient, resulting in a huge increase in power density.
Diabetic foot ulcer is a life-threatening clinical problem in diabetic patients. Endothelial cell-derived small extracellular vesicles (sEVs) are important mediators of intercellular communication in the pathogenesis of several diseases. However, the exact mechanisms of wound healing mediated by endothelial cell-derived sEVs remain unclear. sEVs were isolated from human umbilical vein endothelial cells (HUVECs) pretreated with or without advanced glycation end products (AGEs). The roles of HUVEC-derived sEVs on the biological characteristics of skin fibroblasts were investigated both in vitro and in vivo. We demonstrate that sEVs derived from AGEs-pretreated HUVECs (AGEs-sEVs) could inhibit collagen synthesis by activating autophagy of human skin fibroblasts. Additionally, treatment with AGEs-sEVs could delay the wound healing process in Sprague–Dawley (SD) rats. Further analysis indicated that miR-106b-5p was up-regulated in AGEs-sEVs and importantly, in exudate-derived sEVs from patients with diabetic foot ulcer. Consequently, sEV-mediated uptake of miR-106b-5p in recipient fibroblasts reduces expression of extracellular signal-regulated kinase 1/2 (ERK1/2), resulting in fibroblasts autophagy activation and subsequent collagen degradation. Collectively, our data demonstrate that miR-106b-5p could be enriched in AGEs-sEVs, then decreases collagen synthesis and delays cutaneous wound healing by triggering fibroblasts autophagy through reducing ERK1/2 expression.
We theoretically explored the adsorption and diffusion properties of oxygen and several harmful gases penetrating the graphdiyne monolayer. According to our first-principles calculations, the oxidation of the acetylenic bond in graphdiyne needs to surmount an energy barrier of ca. 1.97 eV, implying that graphdiyne remains unaffected under oxygen-rich conditions. In a broad temperature range, graphdiyne with well-defined nanosized pores exhibits a perfect performance for oxygen separation from typical noxious gases, which should be of great potential in medical treatment and industry.
Contact electrification (triboelectrification) (CE) is a universal phenomenon in ambient environment and has been recorded for more than 2600 years. Nonetheless, the intrinsic mechanism of CE still remains controversial. Herein, based on first-principles theory, the underlying mechanism in CE is systematically investigated between metallic MXenes and semiconductive MoS 2 . The results show that the work functions of contacting materials dominate the direction of electron transfer during CE process. That is, the electron will be transferred from the material with low work function to the one with high work function. The theoretical prediction is verified experimentally through investigating triboelectric probes based on MXenes and MoS 2 nanomaterials. Additionally, it is noted that the interfacial potential barrier and the work function difference together modulate the amount of transferred electron. Electron transfer mainly occurs in the repulsive forces region where the interaction distance between the two materials is shorter than the normal bonding length. The quantum calculation results agree well with the Wang transition theory. Furthermore, it is also noticed that, due to the wave-particle duality of electron, electron transfer will obviously occur at the attractive force region when the two contacting materials exhibit a larger work function difference.
We present a theoretical prediction of a highly efficient membrane for hydrogen purification and natural gas upgrading, i.e. laminar MoS material with triangular sulfur-edged nanopores. We calculated from first principles the diffusion barriers of H and CO across monolayer MoS to be, respectively, 0.07 eV and 0.17 eV, which are low enough to warrant their great permeability. The permeance values for H and CO far exceed the industrially accepted standard. Meanwhile, such a porous MoS membrane shows excellent selectivity in terms of H/CO, H/N, H/CH, and CO/CH separation (>10, > 10, > 10, and > 10, respectively) at room temperature. We expect that the findings in this work will expedite theoretical or experimental exploration on gas separation membranes based on transition metal dichalcogenides.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.