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Zubkov, S. V.; Shapiro, Yu. E.; Сейфулліна, І. Й.; Gorbatyuk, V. Ya.

doi:10.1023/a:1009597010314

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2017

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“…In one of the earliest studies, Thiele described a complex salt of copper with the formula [Cu(AG) 2 ](NO 3 ) 2 , . Similar square‐planar chelate structures have been attributed to complexes of nickel(II), platinum(II), and palladium(II) , . Many energetic nitrogen‐rich aminonitroguanidine (ANQ), containing transition metal salts, M 2+ (ANQ) 2 X 2 (H 2 O)y ( M 2+ = Co, Ni, Cu, Zn; X = nitrate, perchlorate, and dinitramide) were synthesized and characterized as energetic materials .…”

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confidence: 82%

Synthesis, Structural and Energetic Properties of Copper(II) Perchlorate Complex with Aminoguanidine

Mahdavi

Ghani

Nosratzadegan

2017

Zeitschrift anorg allge chemie

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The complexation of copper(II) perchlorate with aminoguanidine hemesulfate (AGHS) yield related mononuclear complex bis(aminoguanidine)copper(II) perchlorate; [Cu(AG) 2 ](ClO 4 ) 2 (I). The characterization of complex I was done by elemental analysis, electronic spectra, IR studies, and X-ray diffraction. From analytical data, a stoichiometry of 1:2 of metal to ligand was determined for the complex. The structure consists of centrosymmetric square planar [Cu(AG) 2 ] 2+ cations and perchlorate counterions. The Cu II atom is * Dr. M. Mahdavi Fax: +98-314-522-0420 E-Mail: m.mahdavi@mut-es.ac.ir [a]

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