1990
DOI: 10.1002/sia.7401601120
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XPS study of MnO2 minerals treated by bioleaching

Abstract: XPS has been used to follow the change of the ore surface composition during bioleaching with a mixed culture of microorganisms. In the original sample, the presence of MOO, togetber with silica and alumina is observed. D u r i n g bioleaching, Mn(IV) is p r e v e l y reduced to Mn(II) and signals due to the presence of the microorganisms appear in the C 1s and N 1s spectra.In the residual sample, a comiderable amount of Ma .ssociated with the cells of the micraorganisms or reprecipitated in the form of the Mn… Show more

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Cited by 37 publications
(20 citation statements)
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“…Moreover, their Al 2p peak positions have visible difference. The Al 2p peak of the AlN film locates at ~74.1 eV, agreeing with the published data [29], while the peak of the etched AlN film is shifted towards the peak of Al-O at ~75.0 eV [30]. This further confirms the oxidation of AlN during deposition, and the internal AlN seems more seriously oxidized.…”
Section: Resultssupporting
confidence: 89%
“…Moreover, their Al 2p peak positions have visible difference. The Al 2p peak of the AlN film locates at ~74.1 eV, agreeing with the published data [29], while the peak of the etched AlN film is shifted towards the peak of Al-O at ~75.0 eV [30]. This further confirms the oxidation of AlN during deposition, and the internal AlN seems more seriously oxidized.…”
Section: Resultssupporting
confidence: 89%
“…For eight samples, the binding energy of Al 2p is mainly at 74.9 eV and Al exists in the form of Al 2 O 3 on particle surface (DiCastro, Polzonetti, Contini, Cozza, & Paponetti, 1990). The binding energy of Cd 3d 5/2 is located at 407.3 eV, which indicating that Cd exists in the form of CdO (Setty & Sinha, 1986).…”
Section: Resultsmentioning
confidence: 98%
“…The fitting peaks are at 642.58 eV and 654.08 eV, which are the characteristic peaks of Mn 4+ 2p 3/2 and Mn 4+ 2p 1/2 , respectively. 16,17 The microstructure and morphology of the Li 4 Mn 5 O 12 -like powders were also observed through field emission scanning electron microscopy (FE-SEM), as shown in Fig. S2a and S2b (ESI †).…”
mentioning
confidence: 99%