XLVI.—Researches on silicon compounds and their derivatives. Part V. On silicotetraphenylamide, para- and ortho-silicotetratolylamides, α- and β-silicotetranaphthylamides

Abstract

REYNOLDS : RESEARCHES ON SILICON COMPOUNDS XLVL-Researches o n Silicon Compounds and their Derivutives. 0% Xilicotetr~p7ienylamide, Pamand Ortho-silicotetratol~l-Part V. anaides, a-and ~-Xilicotetrana~~hthylamides.

Nanostructured Aniline Formaldehyde Resin/Polysilazane Hybrid Materials by Twin Polymerization

“…Triethylamine is used as appropriate base to remove the formed hydrogen chloride. The second monomer tetrakis(phenylamino)silane ( 2 ), which has already been described in literature, is synthesized by the reaction of tetrachlorosilane with aniline in toluene. In this case, an excess of aniline is used as suitable base to remove the developing hydrogen chloride.…”

“…Compound 2 was synthesized according to a modified literature procedure . Aniline (12.42 g, 133 mmol) was dissolved in dried toluene (130 mL) under inert atmosphere and cooled with ice.…”

“…Compound 2 was synthesized according to a modified literature procedure. [34] Aniline (12.42 g, 133 mmol) was dissolved in dried toluene (130 mL) under inert atmosphere and cooled with ice. Silicon tetrachloride (2.50 g, 15 mmol), dissolved in dried toluene (20 mL), was added dropwise to the solution over 20 min.…”