Ammonia
(NH3) is an important chemical in several fields,
such as agriculture, pharmaceutical, material, and chemicals manufacturing.
However, NH3 is a toxic gaseous pollutant and NH3 release results in environment pollution. Minimizing NH3 emission is of great significance for solving NH3-related
environmental issues and promoting the reuse of NH3 resources.
Ionic liquids (ILs) are energy-saving gas absorbents, because of their
low vapor pressure, good chemical stability, and high NH3 solubility. The recent research progress of conventional, functionalized
ILs and novel IL-based materials and solvents for NH3 separation
was summarized. The effects of anions and cations on NH3 absorption capacity, as well as the absorption mechanism of ILs,
were discussed in detail in this Review. The simulated dynamic parameters
of NH3–IL systems including mass diffusivity, heat-
and mass-transfer coefficient were also discussed. In addition, this
Review summarized the industrial application achievement of ILs in
NH3 separation and recovery from NH3-containing
tail gas, which spans from simulation, pilot plant to industrial applications.
Finally, the research trends in NH3 separation by IL-based
systems were proposed based on existing research.