Working together to avoid unwanted reactions: Hydroformylation/O-acylation of terpene-based hydroxyolefins

Delolo, Fábio G.; Vieira, Gabriel Matos; Avendaño-Villarreal, Jesus A.; Dias, Adelson de O.; Santos, Eduardo N. dos; Gusevskaya, Elena V.

doi:10.1016/j.jcat.2023.03.003

Journal of Catalysis

2023

DOI: 10.1016/j.jcat.2023.03.003

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Working together to avoid unwanted reactions: Hydroformylation/O-acylation of terpene-based hydroxyolefins

Fábio G. Delolo

Gabriel Matos Vieira

Jesus A. Avendaño-Villarreal

et al.

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Cited by 5 publications

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One‐Pot Reactions in Different Sites: A New Approach in Hydroformylation‐Based Processes

Delolo,

dos Santos,

Gusevskaya

2024

ChemCatChem

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One‐pot synthetic procedures allow multiple chemical transformations circumventing the isolation of intermediates and thus saving time, energy and feedstocks. Within the scope of one‐pot processes, cascade, domino, or tandem procedures are even more efficient, as multiple reactions can occur in parallel. Hydroformylation is an industrially relevant reaction particularly suitable for this kind of methodology, as the primary products (aldehydes) are usually converted into compounds containing other functionalities. In addition to examples of transformations of the substrate before the hydroformylation step or the transformation of the aldehyde into other functionalities, we highlight a novel approach, in which an additional functionalization takes place in a remote site of the substrate molecule, along with the hydroformylation of the carbon‐carbon double bond.

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One‐Pot Reactions in Different Sites: A New Approach in Hydroformylation‐Based Processes

Delolo,

dos Santos,

Gusevskaya

2024

ChemCatChem

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Production of diacetates from propenylphenols: A one-pot two-step approach involving hydroformylation/hydrogenation/O-acylation

Dias,

Delolo,

Avendaño-Villarreal

et al. 2023

Applied Catalysis A: General

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Catalytic condensation of 3-carene with formaldehyde

Sidorenko,

Kurban,

Khalimonyuk

et al. 2024

Molecular Catalysis

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Working together to avoid unwanted reactions: Hydroformylation/O-acylation of terpene-based hydroxyolefins

Cited by 5 publications

References 28 publications

One‐Pot Reactions in Different Sites: A New Approach in Hydroformylation‐Based Processes

One‐Pot Reactions in Different Sites: A New Approach in Hydroformylation‐Based Processes

Production of diacetates from propenylphenols: A one-pot two-step approach involving hydroformylation/hydrogenation/O-acylation

Catalytic condensation of 3-carene with formaldehyde

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