Production of diacetates from propenylphenols: A one-pot two-step approach involving hydroformylation/hydrogenation/O-acylation

Dias, Adelson de O.; Delolo, Fábio G.; Avendaño-Villarreal, Jesus A.; dos Santos, Eduardo N.; Gusevskaya, Elena V.

doi:10.1016/j.apcata.2023.119369

Applied Catalysis A: General

2023

DOI: 10.1016/j.apcata.2023.119369

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Production of diacetates from propenylphenols: A one-pot two-step approach involving hydroformylation/hydrogenation/O-acylation

Adelson de O. Dias,

Fábio G. Delolo,

Jesus A. Avendaño-Villarreal

et al.

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Cited by 3 publications

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One‐Pot Reactions in Different Sites: A New Approach in Hydroformylation‐Based Processes

Delolo,

dos Santos,

Gusevskaya

2024

ChemCatChem

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One‐pot synthetic procedures allow multiple chemical transformations circumventing the isolation of intermediates and thus saving time, energy and feedstocks. Within the scope of one‐pot processes, cascade, domino, or tandem procedures are even more efficient, as multiple reactions can occur in parallel. Hydroformylation is an industrially relevant reaction particularly suitable for this kind of methodology, as the primary products (aldehydes) are usually converted into compounds containing other functionalities. In addition to examples of transformations of the substrate before the hydroformylation step or the transformation of the aldehyde into other functionalities, we highlight a novel approach, in which an additional functionalization takes place in a remote site of the substrate molecule, along with the hydroformylation of the carbon‐carbon double bond.

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One‐Pot Reactions in Different Sites: A New Approach in Hydroformylation‐Based Processes

Delolo,

dos Santos,

Gusevskaya

2024

ChemCatChem

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Selectivity tuning using Rh/PTABS catalytic system for the hydroformylation of eugenol

Prajapati,

Kapdi,

Sahu

et al. 2024

Catalysis Today

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Aqueous-biphasic catalysis: A technological alternative for the use of organometallic complexes in hydrogenation and hydroformylation reactions with possible industrial application

Baricelli,

Pereira,

Rosales

2025

Catalysis Today

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Production of diacetates from propenylphenols: A one-pot two-step approach involving hydroformylation/hydrogenation/O-acylation

Cited by 3 publications

References 45 publications

One‐Pot Reactions in Different Sites: A New Approach in Hydroformylation‐Based Processes

One‐Pot Reactions in Different Sites: A New Approach in Hydroformylation‐Based Processes

Selectivity tuning using Rh/PTABS catalytic system for the hydroformylation of eugenol

Aqueous-biphasic catalysis: A technological alternative for the use of organometallic complexes in hydrogenation and hydroformylation reactions with possible industrial application

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