Color-tunable
white-light-emitting materials are currently attracting
much attention because of their potential applications in artificial
lighting, sensing, and imaging. However, preparation of these systems
from organic emitters is often cumbersome due to the interchromophoric
interactions occurring upon solvent drying in the final solid materials,
which can be hardly predicted and may lead to detrimental effects.
To circumvent these obstacles, we have developed a new fabrication
methodology that relies on dye encapsulation within liquid-filled
capsules, thus enabling direct transfer of the luminescent properties
from solution to the solid state and as such, rational design of miniaturized
white-light-emitting materials. By introducing a thermally responsive
chromophore into the capsules, these materials are further endowed
with color tunability, which does not only allow ample modulation
of the emitted color but also facilitate external fine control of
the system so as to ensure precise realization of white light at the
desired temperature and excitation wavelength.