Wetting of graphite by molten Cu–xSn–yCr ternary alloys at 1373 K

Lin, Qiaoli; Yang, Fan; Yang, Hong–Yu; Sui, Ran; Shi, Yu; Wang, Jianbin

doi:10.1016/j.carbon.2019.12.097

Cited by 35 publications

(7 citation statements)

References 18 publications

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“…Powder metallurgy (PM) uses the powder of pure metals, blends, or alloys as raw materials, and it produces metallic parts by forming and/or sintering [125][126][127][128][129][130]. Before the process of PM, the powder would be compressed in a mold, which aims to attain the required shapes and dimensions of the model [23,125,[131][132][133]. Afterward, the sintering process is conducted under a protective atmosphere in a high-temperature stove or a vacuum stove.…”

Section: Powder Metallurgymentioning

confidence: 99%

Recent Development in Beta Titanium Alloys for Biomedical Applications

Chen

Cui

Zhang

2020

Metals

182

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β-type titanium (Ti) alloys have attracted a lot of attention as novel biomedical materials in the past decades due to their low elastic moduli and good biocompatibility. This article provides a broad and extensive review of β-type Ti alloys in terms of alloy design, preparation methods, mechanical properties, corrosion behavior, and biocompatibility. After briefly introducing the development of Ti and Ti alloys for biomedical applications, this article reviews the design of β-type Ti alloys from the perspective of the molybdenum equivalency (Moeq) method and DV-Xα molecular orbital method. Based on these methods, a considerable number of β-type Ti alloys are developed. Although β-type Ti alloys have lower elastic moduli compared with other types of Ti alloys, they still possess higher elastic moduli than human bones. Therefore, porous β-type Ti alloys with declined elastic modulus have been developed by some preparation methods, such as powder metallurgy, additive manufacture and so on. As reviewed, β-type Ti alloys have comparable or even better mechanical properties, corrosion behavior, and biocompatibility compared with other types of Ti alloys. Hence, β-type Ti alloys are the more suitable materials used as implant materials. However, there are still some problems with β-type Ti alloys, such as biological inertness. As such, summarizing the findings from the current literature, suggestions forβ-type Ti alloys with bioactive coatings are proposed for the future development.

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Section: Powder Metallurgymentioning

confidence: 99%

Recent Development in Beta Titanium Alloys for Biomedical Applications

Chen

Cui

Zhang

2020

Metals

182

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“…Wang et al first proposed the Sb-Pb alloy as the positive electrode for LMB; the reported Li||Sb-Pb system operated at 450 °C, exhibiting excellent cyclic performance (a capacity retention of 85% after 1800 h cycling) . The environmentally friendly Li||Sb-Sn system was proposed by Li et al, which delivered an average discharge voltage of 0.8 V at 100 mA cm –2 and showed excellent cycle stability at 500 °C. , In the Li||Sb-Sn system, the graphite-based collector is first designed to address the corrosion issues of liquid Sb-Sn alloys during the charge and discharge process of the battery. − However, although the graphite-based collector design effectively solves the corrosion problem of the liquid alloy, the poor wettability of metal/alloy and graphite material results in high contact resistance between liquid electrodes and collector, limiting the efficiency and stability of the battery. − …”

Section: Introductionmentioning

confidence: 99%

In Situ Transition Layer Design Based on Ti Additive Enabling High-Performance Liquid Metal Batteries

Yan

et al. 2023

ACS Appl. Mater. Interfaces

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Liquid metal batteries (LMBs), with the merits of long lifespan and low cost, are deemed as one of the most promising energy storage technologies for large-scale energy storage applications due to the use of liquid metal electrodes and molten salt electrolytes. However, the consequent problem is that the poor wettability between graphite-based collectors and the liquid metal/alloy electrodes leads to large contact resistance, which limits the efficiency and stability of the battery. In this work, a transition layer in situ formed on a graphite-based positive electrode current collector by Ti additive is designed for the first time, which increases the wettability between the positive alloy and the current collector and improves the voltage efficiency of the Li||Sb-Sn cell from 85.6 to 88.4%. These results provide new ideas for the design of high-efficiency LMBs.

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“…Zuo et al [7] constructed a Cu-Fe alloying system where Fe reacted with graphite to form Fe3C layer and the contact angle was reduced from 124°to 21°. Lin et al [8] investigated the wettability of molten Cu-xSn-yCr ternary alloy with graphite at 1373 K and found that both Sn and Cr could reduce the contact angle. Besides, the addition of Cr can significantly improve the wettability.…”

Section: Introductionmentioning

confidence: 99%

Study on the microstructure and properties of copper/graphite composites with two-step method and copper-modified graphite

Ding,

Gao,

Han

et al. 2023

J. Phys.: Conf. Ser.

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In this experiment, copper was coated on the surface of graphite by chemical process. Besides, the microstructure and crystal structure of copper-coated graphite were characterized by SEM and XRD. Copper-plated C/Cu composite was prepared by SPS sintering technique of powder mixture by two-step method. In order to test the dispersion state of graphite in the composites and the phenomenon of interfacial dispersion, the effect of graphite content on the properties of copper-coated C/Cu composites was also an important point. Therefore, the microscopic characterization and performance test were carried out. The results show that magnetic stirring and high-energy ball milling ensure the uniformity of copper-coated graphite in copper matrix, and conducted structural grain refining. The grain size of copper, and the properties of composite materials decreased with the increase of graphite content, such as relative density, conductivity and hardness. However, the further increase of graphite content leads to excessive grain size, the relatively long time of ball milling makes the fine grain become larger after sintering. When the graphite content is 1.0wt.%, the relative density, conductivity and hardness are 99.91%, 92.1%IACS and 67.7 HV, respectively. It is proved that copper-coated graphite and two-step powder mixing play an important role on improving the properties of the composites.

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Wetting of graphite by molten Cu–xSn–yCr ternary alloys at 1373 K

Cited by 35 publications

References 18 publications

Recent Development in Beta Titanium Alloys for Biomedical Applications

Recent Development in Beta Titanium Alloys for Biomedical Applications

In Situ Transition Layer Design Based on Ti Additive Enabling High-Performance Liquid Metal Batteries

Study on the microstructure and properties of copper/graphite composites with two-step method and copper-modified graphite

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