Cutting ceramics with a graded TiC‐rich surface have been obtained by an in situ reaction. Al2O3/TiC ceramics, prepared by reaction sintering, have been subjected to various thermal posttreatments at atmospheric pressure. The temperature, dwelling time, and reaction atmosphere have been varied. It has been observed that a TiC‐rich surface develops in CO‐containing atmospheres. The microstructure of the bulk remains unaffected. Thermal treatment under a CO atmosphere at 1600°C for 1 h resulted in a dense TiC layer on the ceramic. A schematic model is proposed for this layer formation process.