2004
DOI: 10.1103/physrevb.69.132407
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Weak ferromagnetism inCaB6

Abstract: We have combined the results of magnetization and Hall effect measurements to conclude that the ferromagnetic moments of lightly doped CaB 6 samples display no systematic variation with electron doping level. Removal of the surface with acid etching substantially reduces the measured moment, although the Hall constant and resistivity are unaffected, indicating that the ferromagnetism largely resides on and near the sample surface. Electron microprobe experiments reveal that Fe and Ni are found at the edges of … Show more

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Cited by 33 publications
(19 citation statements)
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“…Conclusive evidence for intrinsic ferromagnetism in semiconductors is highly nontrivial. For example, early work reporting ferromagnetism even at nearly 900 K in La-doped CaBa 6 Ott et al, 2000;Tromp et al, 2001), was later revisited suggesting extrinsic effect (Bennett et al, 2003). It remains to be understood what the limitations are for using extrinsic ferromagnets and, for example, whether they can be effective spin injectors.…”
Section: B Materials Considerationsmentioning
confidence: 99%
“…Conclusive evidence for intrinsic ferromagnetism in semiconductors is highly nontrivial. For example, early work reporting ferromagnetism even at nearly 900 K in La-doped CaBa 6 Ott et al, 2000;Tromp et al, 2001), was later revisited suggesting extrinsic effect (Bennett et al, 2003). It remains to be understood what the limitations are for using extrinsic ferromagnets and, for example, whether they can be effective spin injectors.…”
Section: B Materials Considerationsmentioning
confidence: 99%
“…[3][4][5] The Curie temperature there was 900 K. Subsequent studies of highly pure powder showed no measurable ferromagnetism, 6 the effect was attributed to traces of iron or iron boride in the crystals. 7,8 Nonetheless, there are persistent indications of small ferromagnetic moments in CaB 6 , which depend on sample stoichiometry and heat treatment. 4,6,9 We recently observed large moments in disordered thin films of CaB 6 and SrB 6 .…”
Section: Introductionmentioning
confidence: 99%
“…The hypothesis that extraneous ferromagnetic phases are the source of the ferromagnetism can be excluded on the basis of the data at hand: (i) iron is the most likely ferromagnetic contaminant, 11,13 but an Fe/ Ca atomic ratio exceeding 100% would be needed to explain the magnetization of the thinnest CaB 6 less than 3%; (ii) much smaller moments are observed for CaB 6 films on MgO which proves that no extraneous ferromagnetism arises from the substrate or deposition process; and (iii) an anisotropy of the ferromagnetism found in some of the films is quite unlike that of any known ferromagnetic phase, although it is similar to that discovered in thin films of What then is the origin of this remarkable ferromagnetism? The data suggest that the effect is governed by the material/substrate combination.…”
mentioning
confidence: 99%