Waste biomass-derived carbon-supported palladium-based catalyst for cross-coupling reactions and energy storage applications

Kempasiddaiah, Manjunatha; Raj, Kalyan; Kandathil, Vishal; Dateer, Ramesh B.; Sasidhar, B. S.; Yelamaggad, C. V.; Rout, Chandra Sekhar; Patil, Siddappa A.

doi:10.1016/j.apsusc.2021.151156

Cited by 25 publications

(6 citation statements)

References 76 publications

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“…In addition, the BC-TPEA@Pd catalyst was recovered after the reaction was finished, and an ICP-OES analysis of the reaction mass revealed a less than 0.1 ppm Pd concentration. This demonstrated that the Pd NPs are securely attached to the catalyst support, making them less vulnerable to the leaching of Pd NPs from the support surface during the reaction [130].…”

Section: Figure 24mentioning

confidence: 97%

Biomass-Derived Carbon Materials in Heterogeneous Catalysis: A Step towards Sustainable Future

et al. 2022

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Biomass-derived carbons are emerging materials with a wide range of catalytic properties, such as large surface area and porosity, which make them ideal candidates to be used as heterogeneous catalysts and catalytic supports. Their unique physical and chemical properties, such as their tunable surface, chemical inertness, and hydrophobicity, along with being environmentally friendly and cost effective, give them an edge over other catalysts. The biomass-derived carbon materials are compatible with a wide range of reactions including organic transformations, electrocatalytic reactions, and photocatalytic reactions. This review discusses the uses of materials produced from biomass in the realm of heterogeneous catalysis, highlighting the different types of carbon materials derived from biomass that are potential catalysts, and the importance and unique properties of heterogeneous catalysts with different preparation methods are summarized. Furthermore, this review article presents the relevant work carried out in recent years where unique biomass-derived materials are used as heterogeneous catalysts and their contribution to the field of catalysis. The challenges and potential prospects of heterogeneous catalysis are also discussed.

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Section: Figure 24mentioning

confidence: 97%

Biomass-Derived Carbon Materials in Heterogeneous Catalysis: A Step towards Sustainable Future

et al. 2022

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“…Ferlin and coworkers 30 report on the development of a waste minimization/valorization methodology used to the representative benchmark Sonogashira reaction conducted in a continuous-flow reactor, featuring a continuous-flow downstream membrane organic/aqueous separator to recover medium and products with minimal waste. Kempasiddaiah et al 31 reported the synthesis of low-cost mesoporous biomass carbon from waste radish leaves and was employed as support in preparing a palladium-based (BC-TPEA@Pd) heterogeneous catalyst.…”

Section: Introductionmentioning

confidence: 99%

Preparation of magnetic biochar functionalized by polyvinyl imidazole and palladium nanoparticles for the catalysis of nitroarenes hydrogenation and Sonogashira reaction

Mohammadi,

Heravi,

Mohammadi

et al. 2023

Sci Rep

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Catalysts are essential materials in biotechnology, medicine, industry, and chemistry. On the other hand, recycling and using waste materials is important in economic efficiency and green chemistry. Thus, biochar was prepared from the stem and roots of the Spear Thistle to recover waste. After magnetizing the biochar, its surface was modified with polyvinyl imidazole. Finally, this modified biochar was decorated with Pd nanoparticles and used as a selective and recyclable nanocatalyst in the hydrogenation of nitroarenes and the Sonogashira reaction. The structure of this organic–inorganic nanocatalyst has been characterized by FESEM-EDS, XRD, FT-IR, TEM, and VSM techniques. In the hydrogenation reaction with the amount of 30 mg of nanocatalyst, the temperature of 50 °C in the water solvent, the reaction efficiency reached 99% for 30 min. In addition, under optimal conditions for the Sonogashira reaction: 1.0 mmol iodobenzene, 1.2 mmol phenylacetylene, 20 mg MBC-PVIm/Pd, 2 mmol K2CO3 in H2O at 50 C for 15 min, the reaction efficiency reached 95%. The recyclability of magnetic nanocatalysts was investigated and recognized this nanocatalyst can be used several times without notable loss of its activity.

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“…The Suzuki products are widely used in the pharmaceutical industry, natural and pharmaceutical compounds, conductive polymers, sensors and dyes. Therefore, in recent years many researchers have studied and evaluated the optimization of this reaction using efficient catalytic systems ( Dong et al, 2021 ; Favalli et al, 2021 ; Kempasiddaiah et al, 2021 ; Kim et al, 2021 ). Some of recently reported catalysts in this matter are Fe 3 O 4 @SiO 2 @NHC@Pd-MNPs ( Akkoç et al, 2021 ), Fe 3 O 4 /Pd ( Veisi et al, 2021 ), Fe 3 O 4 @SiO 2 /glucosamine-Pd ( Eslahi et al, 2021 ), SiO 2 -NH 2 @Pd (dpa)Cl 2 ( Aghahosseini et al, 2021 ), Fe 3 O 4 /SiO 2 -NH 2 @CS/Pd ( Veisi et al, 2020 ), Fe 3 O 4 @MCM-41-SB/Pd ( Shaker and Elhamifar, 2020a ), PEt@ IL/Pd ( Kargar and Elhamifar, 2020 ), GO-N 2 S 2 /Pd ( Zarnegaryan and Elhamifar, 2020 ) and GO–SB/Pd ( Zarnegaryan et al, 2019 ).…”

Section: Introductionmentioning

confidence: 99%

Magnetic ethylene-based periodic mesoporous organosilica supported palladium: An efficient and recoverable nanocatalyst for Suzuki reaction

Neysi

Elhamifar²

2023

Front. Chem.

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In the present study, a novel magnetic ethylene-based periodic mesoporous organosilica supported Pd-Schiff base complex (Fe3O4@PMO/SB-Pd) was prepared, characterized and applied as a recoverable nanocatalyst for green synthesis of Suzuki products. Chemical composition, magnetic and thermal behavior, morphology and particle size of Fe3O4@PMO/SB-Pd were investigated by using FT-IR, TGA, EDX, VSM, PXRD, TEM and Scanning electron microscopy (SEM) analyses. The Fe3O4@PMO/SB-Pd nanocomposite was applied as an efficient nanocatalyst in the Suzuki reaction under ultrasonic conditions giving corresponding products in high yield. Some advantages of this study are simple purification of products, the use of water solvent, easy catalyst separation, short reaction time and high catalyst efficiency and recoverability.

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Waste biomass-derived carbon-supported palladium-based catalyst for cross-coupling reactions and energy storage applications

Cited by 25 publications

References 76 publications

Biomass-Derived Carbon Materials in Heterogeneous Catalysis: A Step towards Sustainable Future

Biomass-Derived Carbon Materials in Heterogeneous Catalysis: A Step towards Sustainable Future

Preparation of magnetic biochar functionalized by polyvinyl imidazole and palladium nanoparticles for the catalysis of nitroarenes hydrogenation and Sonogashira reaction

Magnetic ethylene-based periodic mesoporous organosilica supported palladium: An efficient and recoverable nanocatalyst for Suzuki reaction

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