Vom Fluorsilan zum Siloxan — 1,3-Silylgruppenwanderung am Si3CSiO-Gerüst/ From a Fluorosilane to a Siloxane — 1,3-Migration of Silyl Groups in the Si3CSiO System
Abstract:AbstractThe nature of the products which are formed in the reaction of tris(trimethylsilyl)Methylfluorosilanes (Me3Si)3C -SiF2R with KOH depends on the bulkiness of the substituents R. The condensed siloxane is obtained for R = F . The crystal structure determination of this siloxane (Me3Si)3C -SiF2-O -SiF2-C (SiMe3 Show more
“…Sterically protected fluorosilanes have been employed as valuable starting materials for the synthesis of multiple bonded silicon species and/or novel polyfunctional silicon compounds [1][2][3][4][5][6][7][8][9][10]. For silanes, steric protection is usually effected by bulky ligands directly attached to the silicon atom.…”
“…Sterically protected fluorosilanes have been employed as valuable starting materials for the synthesis of multiple bonded silicon species and/or novel polyfunctional silicon compounds [1][2][3][4][5][6][7][8][9][10]. For silanes, steric protection is usually effected by bulky ligands directly attached to the silicon atom.…”
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