“…Specifically, the Kolbe electrolysis enables the upgrading of n ‐CA mixtures, originated from microbial conversions of a variety of substrates such as corn beer, [13] acid whey, [12] or other organic waste streams[ 30 , 31 , 32 ] to fuels or fuel additives. In general, the combination of microbial and electrochemical conversion in electrobiorefineries offers the potential to make an important contribution to a circular and bio‐based but also viable economy.…”
Mixtures of n-carboxylic acids (n-CA) as derived from microbial conversion of waste biomass were converted to bio-fuel using Kolbe electrolysis. While providing full carbon and electron balances, key parameters like electrolysis time, chain length of n-CA, and pH were investigated for their influence on reaction efficiency. Electrolysis of n-hexanoic acid showed the highest coulombic efficiency (CE) of 58.9 � 16.4 % (n = 4) for liquid fuel production among individually tested n-CA. Duration of the electrolysis was varied within a range of 0.27 to 1.02 faraday equivalents without loss of efficiency. Noteworthy, CE increased to around 70 % by hetero-coupling when electrolysing n-CA mixtures regardless of the applied pH. Thus, 1 L of fuel could be produced from 12.4 mol of n-CA mixture using 5.02 kWh (< 1 E L À 1 ). Thus, a coupling with microbial processes producing n-CA mixtures from different organic substrates and waste is more than promising.
“…Specifically, the Kolbe electrolysis enables the upgrading of n ‐CA mixtures, originated from microbial conversions of a variety of substrates such as corn beer, [13] acid whey, [12] or other organic waste streams[ 30 , 31 , 32 ] to fuels or fuel additives. In general, the combination of microbial and electrochemical conversion in electrobiorefineries offers the potential to make an important contribution to a circular and bio‐based but also viable economy.…”
Mixtures of n-carboxylic acids (n-CA) as derived from microbial conversion of waste biomass were converted to bio-fuel using Kolbe electrolysis. While providing full carbon and electron balances, key parameters like electrolysis time, chain length of n-CA, and pH were investigated for their influence on reaction efficiency. Electrolysis of n-hexanoic acid showed the highest coulombic efficiency (CE) of 58.9 � 16.4 % (n = 4) for liquid fuel production among individually tested n-CA. Duration of the electrolysis was varied within a range of 0.27 to 1.02 faraday equivalents without loss of efficiency. Noteworthy, CE increased to around 70 % by hetero-coupling when electrolysing n-CA mixtures regardless of the applied pH. Thus, 1 L of fuel could be produced from 12.4 mol of n-CA mixture using 5.02 kWh (< 1 E L À 1 ). Thus, a coupling with microbial processes producing n-CA mixtures from different organic substrates and waste is more than promising.
“…VFAs including caproate, valerate, butyrate, propionate and acetate were detected by Gas Chromatography and the concentrations of glucose, fructose and lactate were determined by high-performance liquid chromatography, as described previously by Selder et al (2021). The optical density (OD) was measured with a spectrophotometer (Shimadzu UV-1201 & UV-Vis, Australia) at wavelength 630 nm.…”
Section: Methodsmentioning
confidence: 99%
“…In the enzymatic hydrolysis, all parts of the cabbage were utilized. Hydrolysis was performed as previously described by Selder et al (2021). The composition for cabbage hydrolysate (Cab1 medium) is 17.6 ± 0.1 g L −1 of fructose and 27.8 ± 0.1 g L −1 of glucose with a dry matter content of 6.6 ± 0.03 %.…”
Section: Selected Strains For Vfa Production and Food Waste Character...mentioning
confidence: 99%
“…Instead of adding extra glucose or fructose to increase their concentration in the waste stream, the total sugar concentration was kept constant while the glucose to fructose ratio was modified. The medium was changed from Cab1 to Cab2 (Section 2.1), since in parallel with the development of the model, the production process itself was optimized by Selder et al (2021). Due to the change in glucose and fructose concentrations, the ratio between glucose and fructose initial concentration was assumed to be 1.0 in all in silico experiments.…”
Section: Targeting the Production Of Odd-and Even Carbon Vfas In In S...mentioning
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