Omnidirectional broadband terahertz (THz) antireflection
(AR) with
an actively configurable coating promises the achievement of next-generation
efficient and versatile THz components with high performance. We demonstrate
a near-infrared (NIR) light-tunable and omnidirectional broadband
THz AR coating based on an impedance matching method and composed
of a poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS)/graphene
composite film. The omnidirectional broadband properties of the active
AR coating can be efficiently achieved by tunable NIR optical excitation
of less than 0.27 W·cm–2, which exhibits omnidirectional
suppression of THz-wave reflection for incidence angles from 0 to
70°, concerning the broadband frequency range of 0.1–3.0
THz, with an ultrafast response time of ∼5 ps. Furthermore,
we demonstrate that the active AR coating can improve the performance
of a reflectance-tunable THz-wave polarization reflector by the elimination
of Fabry–Pérot interference. The NIR irradiance-dependent
active AR mechanism of the hybrid system is investigated, which demonstrates
the essential role of the PEDOT:PSS/graphene layers in promoting the
charge separation at the interface and therefore changing the photoconductivity
of the composite film to achieve impedance matching under optical
excitation. Several crucial advantages of the proposed and proven
concept, including the wide-angle range, broad spectral range, flexible
tunability, and easier fabrication, may revolutionize the AR strategy
at THz frequencies for a wide range of THz applications.