“…Pyrophophates A IV M 2 V O 7 , where the A IV cation includes Zr, Ti, Mo, Re, W, Th, U, Pu, Ce, Hf, Pb, Sn, Ge, and Si; M V = P, V, or As, are known for their unusual high temperature behaviour. [13] Thermal expansion is a necessary consideration in a number of applications where increases and decreases in temperatures can affect physical dimensions, stability, integrity, and mechanical properties of materials. To the best of our knowledge, there are no dedicated reports of controlled metal-phosphate nanomaterial synthesis through organometallic syntheses and subsequent procedures.…”