1960
DOI: 10.1007/bf02731914
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Vapour pressure of isotopic liquids

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Cited by 23 publications
(4 citation statements)
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“…The liquid-vapor isotope fractionation factor for a near classical fluid is directly related to the difference in the means of the Laplacian of the 11 12 potential energy in the liquid and vapor phases respectively. ' £na = ij (fi/kT) 2 ({j,~) t<V 2 U> c~< V 2 U> g ] (…”
Section: Introductionmentioning
confidence: 99%
“…The liquid-vapor isotope fractionation factor for a near classical fluid is directly related to the difference in the means of the Laplacian of the 11 12 potential energy in the liquid and vapor phases respectively. ' £na = ij (fi/kT) 2 ({j,~) t<V 2 U> c~< V 2 U> g ] (…”
Section: Introductionmentioning
confidence: 99%
“…2, α 39−40 was calculated from the measured value of α 36−40 . Another publication [17] reports a lower value of α 36−40 than that reported in Sect. 2, that would lead to α 39−40 =1.0013 at the mean operating temperature of the column of 89.5 K. At this value one would have a decrease in B by about 25%.…”
Section: Measurement Interpretationmentioning
confidence: 74%
“…These corrections were applied using the thermodynamic data given by McCarty and Stewart [9]. The term in square brackets ranged from 0-970 at 24.7 K to 0"595 at 38-6 K. The isotope separation factor has also been measured directly by mass spectrometric analysis of samples withdrawn from a system at equilibrium by Boato et al [14][15][16]. This work is in good agreement with In a values obtained from the work of Bigeleisen and Roth.…”
Section: Radial Distribution [Unctionsmentioning
confidence: 99%