Valence band and magnetic moment of Mn in TbMn2 and TbMn2D2 studied by Kβ5 emission X-ray spectroscopy

Jarocki, E.; Kozłowski, A.; Figiel, H.

doi:10.1016/j.jallcom.2004.11.115

Cited by 3 publications

(2 citation statements)

References 13 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The d-states of manganese have been probed using K b5 X-ray fluorescence spectra. 33 In both of the examined Tb-Mn compounds, the intensities of K b5 lines are greatly reduced in comparison with elemental manganese.…”

Section: Manganesementioning

confidence: 90%

Manganese, technetium and rhenium

West

2006

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

View full text Add to dashboard Cite

The first complex containing three-coordinate manganese(I) that contains a Mn-Mn bond has been reported. The compound was synthesised by reduction of a bis(m-iodo)dimanganese(II) complex, and exhibits unusual magnetic properties and an antiferromagnetic interaction between the metal centres. A novel glucosamine-dipicolylamine conjugate of 99m Tc(I) has been prepared. This complex has ideal properties for therapeutic applications as it is easily characterised, stable and kinetically inert and contains an N-functionalised glucosamine, a carbohydrate derivative that has been shown to accumulate in tumours. A sterically demanding, soluble rhenium m 2 -pyrazolate complex has been synthesised and shown to be active in catalysis. The complex was successfully used in the oxidation of triphenylphosphine and the epoxidation of cyclooctene, with very high catalytic rates being observed.

show abstract

Section: Manganesementioning

confidence: 90%

Manganese, technetium and rhenium

West

2006

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

View full text Add to dashboard Cite

show abstract

“…Ying and Chen 414 studied the peak position and line shape of S Ka, S Kb satellite lines and the ratio of (S Ka/S Kb), (Cu La/ Cu Ka) and (Fe La/Fe Ka) of copper ore concentrate samples to show that the oxidation state was influenced by the method of storage. Jarocki et al 415 measured Mn Kb 5 spectra for Mn metal, TbMn 2 and TbMn 2 D 2 . The Kb 5 lines in the Tb-Mn compounds were reduced to one third of those in the elemental Mn.…”

Section: Chemical State Speciation and Crystal Characterisationmentioning

confidence: 99%