Photolysis via vacuum ultraviolet
(VUV) irradiation is a robust
technology capable of inactivating pathogens and degrading micropollutants,
and therefore, its application has recently attracted great interest.
However, VUV irradiation of water may yield nitrite (NO2
–, a regulated carcinogenic contaminant) and hydrogen
peroxide (H2O2, a compound linked to aging,
inflammation, and cancer), thus motivating us to better understand
its risks. By applying a novel H2O2 detection
method insensitive to coexisting compounds, this study clearly observed
concurrent and substantial formations of NO2
– and H2O2 during VUV irradiation of various
synthetic and real waters. Increasing pH and/or decreasing oxygen
promoted the conversion of nitrate (NO3
–) into NO2
– but suppressed the H2O2 formation, suggesting that there was a transition
of radicals from oxidizing species like hydroxyl radicals to reducing
species like hydrogen atoms and hydrated electrons. Under low light
dose conditions, both NO2
– and H2O2 were formed concurrently; however, under high
radiation dosage conditions, the patterns conducive to NO2
– formation were opposite to those conducive to
H2O2 formation. Real water irradiation proved
the formation of NO2
– and H2O2 at levels near to or greater than current drinking
water regulatory limits. Hence, the study reminds of a holistic view
of benefits and disbenefits of a VUV process.