Ceaselessly
increasing demands for elaborate nanostructures prompt
advanced structure fabrication with good practicability, especially,
subwavelength ordered structures in simple lattices even in superlattices
over a large area, namely, large-scale photonic lattices, in which
lattice arrangement, geometry, and components of unit cells are key
factors for their macroscopic optical properties. Moreover, exciting
properties always occur at high symmetry points of the lattice; therefore,
straightforward modulation of symmetry points over a large area is
very important for the investigation and application of photonic lattices.
Here, this work establishes a lithography-free approach of undervoltage
oxidation (UVO) for regulating high symmetry points in the reciprocal
space of a dielectric alumina superlattice. Embedding subunit cells
at high symmetry points Γ (M) result in the degenerate energy changing from 1.34 eV (924.6 nm)
to 1.87 eV (662.6 nm) under normal excitation at the Γ point, and the degeneracy lifting under off-normal excitation along
the Γ–X high symmetry
orientation. Furthermore, systematic characterizations of the alumina
membrane are presented to learn its dynamic evolution of the morphology
on a centimeter scale, and the pore array changes from a hierarchical
period to a form of hexagonal close packing, especially at Γ and M points of the square lattice.
Therefore, the reported lithography-free alumina-based nanofabrication
offers an ability for varying the spatial structure at high symmetry
points of photonic lattices, which is of great significance in the
fields of nanomanufacturing and has great potential to bring about
preferable performances in nanodevices.