Using the Reactions O+H₂ → OH+H to Explore the Importance of the Atomic Quantum States on Chemical Kinetics and Reaction Dynamics

Abstract

The O + H 2 reaction is a particular example to alert the importance of a clear definition of the quantum state of an atom when referring to a chemical reaction. In its ground state, O ( 3 P), the oxygen atom reacts with H 2 through an energy barrier with small rate constant. In contrast, when the oxygen atom is in its first excited state, O ( 1 D), the reaction O + H 2 occurs without energy barrier and the rate constant is seven orders of magnitude higher. The dynamic behaviour of this reaction depends also on the quantum state of the oxygen atom.