Landfills are major contributors to the atmospheric CH4
budget. A major uncertainty in estimating CH4 flux from
landfills is determining the attenuation of CH4 emission by
methanotrophic bacteria in the aerobic outer portions of
the cover soil. These bacteria intercept the gas as it migrates
toward the atmosphere. To estimate cover soil oxidation,
we made seasonal measurements of the difference in the
δ13C of CH4 within the anoxic zone and CH4 released
from landfills and captured downwind at two landfills in
the Northeastern United States. Anoxic zone CH4 at the
Nashua Landfill averaged −54.6 ± 0.7‰, n = 205, and
displayed no significant seasonal pattern. Methane was
in excess over ambient air concentrations in the downwind
plume ranging from 2.13 to 3.41 ppmv. The δ13C of
excess CH4, as determined by mass balance with correction
for ambient air CH4, varied from −49.35 to −54.28‰. We
used these values to calculate soil CH4 oxidation, which
ranged from 0 to 23.6%. Oxidation was greatest in the
summer and in the fall, with an annual value of 12 ± 8%.
At a second landfill, plume CH4 ranged from 1.96 to 2.92
ppmv with excess δ13C values of −52.17 to −58.06‰. Oxidation
at this landfill ranged from 0 to 14%.