Pump-induced dynamical tunneling has been observed in free-space resonant optical pumping of a deformed microcavity by employing excitation spectroscopy. A focused-pump beam was injected into the cavity by refraction and then coupled to a high-Q cavity mode via dynamical tunneling. Pump-coupling efficiency as high as 50% and an effective coupling constant responsible for the tunneling were obtained from the observed pumping efficiency with a mode-mode coupling model. DOI: 10.1103/PhysRevLett.104.243601 PACS numbers: 42.55.Sa, 03.65.Xp, 05.45.Mt, 42.50.Àp Efficient optical pumping of high-Q cavity modes is of primary concern in microcavity applications such as microlasers and optoelectronic components and devices [1]. Prism and tapered-fiber couplings are commonly used for ultrahigh-Q whispering gallery modes [2,3]. However, simple free-space coupling without near-field couplers is often needed for practical reasons such as experimental limitations or implementation cost. Microcavities deformed from rotational symmetry can provide directional emission of high-Q modes, and, moreover, allow one to excite them by a free-space pump beam. Recently, cryogenic cooling of an optomechanical resonator assisted by free-space evanescent coupling has been reported in a slightly deformed microsphere [4]. Efficient nonresonant optical pumping based on ray chaos has also been demonstrated in deformed microcavities [5,6], suggesting further enhancements by resonant optical pumping.In a significantly deformed microcavity, the ray dynamics typically exhibits both regular and chaotic trajectories [7], resulting in a mixed phase space: high-Q modes are usually localized on regular regions such as invariant tori and regular islands surrounded by a chaotic sea. It is known that light in high-Q modes localized on those regular regions can be transferred to the nearest chaotic sea by a dynamical process and then transported by ray chaos resulting in a directional refractive output. The dynamical process is called dynamical tunneling [8] since the transport from a regular region to the chaotic sea is strictly forbidden classically.The dynamical tunneling is thus an essential link between high-Q modes and directional output, important assets for the aforementioned photonic applications. In fact, dynamical tunneling is of great current interest and has been studied theoretically in various physical systems [9][10][11][12][13][14]. Experimental signatures of dynamical tunneling were reported in a microwave billiard in energy splitting [15,16], in an acoustical resonator through spectral statistics [17], and in a cold atomic sample in atomic momentum distribution [18,19]. In microcavities, although it has been studied theoretically [20][21][22][23], there is no direct experimental evidence for dynamical tunneling.How can then the dynamical tunneling be used to improve the optical pumping? The answer lies in the reverse of the aforementioned output process. If we inject a pump beam in a time reversed way, the pump light might be transferre...