The sulphate doped polypyrrole (PPy) is encapsulated over the tin nano particles using ammonium per sulphates as a polymerizing agent. The XRD, SEM and HRTEM analysis confirms the formation of Sn-PPy composite. Laser Raman and FTIR evidenced for bi-polaron. The conductive PPy prevents the isolation of Sn from the conductive wire, which act as a current collector and backbone as well. The Sn-PPy composites exhibits nominal reversible capacity 698, 878, 791 and 842 mAh g-1 for bare Sn, 80:20, 90:10 and 95:5 Sn-PPy respectively at 100 mA g-1. 80:20 Sn-PPy exhibits superior performance at different current densities. At 400 mA g-1 it delivers ~300 mAh g-1 with the capacity retention of 96% over the studied 50 cycles. The charge transfer resistance for the Sn-PPy 80:20 composite showing comparatively lesser value ~39 Ω. Thus, the composite’s anodic characteristics is well pronounced to be used in lithium ion batteries.