Understanding and suppression strategies toward stable Li metal anode for safe lithium batteries

Yasin, Ghulam; Arif, Muhammad; Mehtab, Tahira; Lu, Xia; Yu, Donglin; Muhammad, Noor; Nazir, M. Tariq; Song, Huaihe

doi:10.1016/j.ensm.2019.09.020

Cited by 232 publications

(110 citation statements)

References 366 publications

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“…These chemicals are harmful to humans and the environment. Hence, finding alternatives to these toxic substances is considered significant for the interest of researchers and socio-economic development [ 4 , 5 , 6 , 7 , 8 , 9 , 10 ].…”

Section: Introductionmentioning

confidence: 99%

Water-Borne ZnO/Acrylic Nanocoating: Fabrication, Characterization, and Properties

Nguyen

Tabish

et al. 2021

Polymers

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This work aims to explore how ZnO nanoparticles enhance the mechanical, photoaging, and self‑cleaning properties of water‑borne acrylic coating. Micro/nano‑ZnO particles (at 2 wt.% of total solid resin) were dispersed into the acrylic polymer matrices using ultrasonication to understand the effect of the size of the coating properties. The effect of ZnO particles on the properties of composite coatings (25 µm of thick) have been evaluated through various tests, such as abrasion measurement, ultraviolet/condensation (UV/CON) weathering aging, and methylene blue self‑cleaning. Experimental data indicated that the incorporation of ZnO particles enhanced both abrasion resistance and methylene blue removal efficiency of the water‑borne acrylic coatings, with nano‑ZnO particles being the best. However, the weathering degradation of nanocomposite coatings was more severe as compared to the coating with micro‑ZnO (at the same ZnO content).

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Section: Introductionmentioning

confidence: 99%

Water-Borne ZnO/Acrylic Nanocoating: Fabrication, Characterization, and Properties

Nguyen

Tabish

et al. 2021

Polymers

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“…For the other metal anodes, a variety of strategies, such as alloy anodes, structural anode design, solid electrolytes, and surface coating, still must be used to protect the anode. [ 98 ] For the metal‐free anode materials, research on the selectivity of anode materials for different metal ions is overlooked. As an important property for anode materials, multi‐accessibility for metal ions can offer an alternative path for the development of energy storage system and further enhance the electrochemical performance of HMIB.…”

Section: Conclusion and Perspectivementioning

confidence: 99%

Rechargeable Sodium‐Based Hybrid Metal‐Ion Batteries toward Advanced Energy Storage

Yang

Liu

et al. 2020

Adv Funct Materials

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Growing demands on energy storage devices have inspired a tremendous amount of research on rechargeable batteries. Future generations of rechargeable batteries are required to have high energy density, long lifespan, low cost, high safety, low environmental impact, and wide commercial affordability. To achieve these goals, significant efforts are underway to focus on electrolyte chemistry, electrode engineering, and new designs for energy storage systems. Herein, a comprehensive overview of an innovative sodium‐based hybrid metal‐ion battery (HMIBs) for advanced next‐generation energy storage is presented. Recent advances on sodium‐based HMIBs from the development of reformulated or novel materials associated with Na+ ions and other metal ions (such as Li+, K+, Mg2+, Zn2+, etc.), are summarized in this work. Daniell cell and “rocking‐chair” type batteries are covered. Finally, the current challenges and future remedies in terms of the design and fabrication of new electrolytes, cathodes, and anodes for advanced HMIBs are discussed in this report.

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“…[1][2][3] However, the limited lithium resources increase the cost; dendrite formation of metallic lithium leads to some safety risks; and their energy density needs to be higher than currently available. [4][5][6] Those issues severely restrict the further development of lithium-ion batteries, [7] which inspires the investigations for some alternative energy storage systems, such as lithium-sulfur, [8,9] sodium-ion, [10,11] potassium-ion, [12] aluminum-ion, [13] and magnesium (Mg) batteries. [14] Among them, rechargeable Mg batteries have attracted broad attention owing to their high theoretical capacity (3833 mAh cm −3 and 2205 mAh g −1 ), low electrode potential (-2.36 V vs standard hydrogen electrode), abundance of Mg (10 4 times more than lithium by weight), good chemical stability without dendrite formation, and environmental friendliness.…”

Section: Doi: 101002/advs202002298mentioning

confidence: 99%

General Liquid‐Driven Coaxial Flow Focusing Preparation of Novel Microcapsules for Rechargeable Magnesium Batteries

et al. 2020

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Magnesium batteries have been considered promising candidates for next‐generation energy storage systems owing to their high energy density, good safety without dendrite formation, and low cost of magnesium resources. However, high‐performance cathodes with stable capacity, good conductivity, and fast ions transport are needed, since many conventional cathodes possess a low performance and poor preparation controllability. Herein, a liquid‐driven coaxial flow focusing (LDCFF) approach for preparing a novel microcapsule system with controllable size, high loading, and stable magnesium‐storage performance is presented. Taking the MoS2‐infilled microcapsule as a case study, the magnesium battery cathode based on the microcapsules displays a capacity of 100 mAh g−1 after 100 cycles. High capacity retention is achieved at both low and high temperatures of −10, ‒5, and 45 °C, and a stable rate‐performance is also obtained. The influences of the liquid flow rates on the size and shell thickness of the microcapsules are investigated; and electron and ion diffusion properties are also studied by first‐principle calculations. The presented LDCFF method is quite general, and the high performance of the microcapsules enables them to find broad applications for making emerging energy‐storage materials and secondary battery systems.

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Understanding and suppression strategies toward stable Li metal anode for safe lithium batteries

Cited by 232 publications

References 366 publications

Water-Borne ZnO/Acrylic Nanocoating: Fabrication, Characterization, and Properties

Water-Borne ZnO/Acrylic Nanocoating: Fabrication, Characterization, and Properties

Rechargeable Sodium‐Based Hybrid Metal‐Ion Batteries toward Advanced Energy Storage

General Liquid‐Driven Coaxial Flow Focusing Preparation of Novel Microcapsules for Rechargeable Magnesium Batteries

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