PACS: 78.55.CrEvolution of photoluminescence spectra in quaternary AlInGaN alloys is studied as a function of indium content. An emergence of an S-shaped temperature dependence of the luminescence peak position and a W-shaped temperature dependence of the line width was observed with a gradual increase of the In molar fraction. This infers that the incorporation of indium into AlGaN results in formation of a network of states that facilitate exciton localization and hopping typical of ternary InGaN.Development of deep UV light emitters is emerging as one of the most important applications for III-nitride based optoelectronics. It stimulates studies of quaternary AlInGaN alloys, which offer a unique control over energy band tailoring and strain and polarization engineering in heterostructures and quantum wells [1][2][3]. A newly developed pulsed atomic layer epitaxy (PALE) [4] and pulsed metalorganic chemical vapor deposition (PMOCVD) [5] techniques allow one to accurately control the quaternary layer composition and thickness. In particular, the PALE technique allowed us to fabricate LEDs emitting at wavelengths as short as 305 nm [6]. It has also been demonstrated that incorporation of indium into AlGaN decreases potential fluctuations and increases the diffusion length of photoexcited carriers [7], as well as markedly enhances UV emission [8][9][10].In spite of strong implications for the crucial role of indium in improving the radiative properties of nitride alloys with high Al molar fraction, the physical reasons of this phenomenon are not completely understood. To clarify the underlying physics of light emission from quaternary AlInGaN alloys, we examined the variation of photoluminescence temperature behavior with gradual incorporation of In into AlGaN. Here, we report on the emerging of an S-shaped temperature dependence of the luminescence peak position and a W-shaped temperature dependence of the line width with increasing In molar fraction from 0 to 2%. This indicates that the formation of quaternary AlInGaN alloy results in the band potential profile and transport pattern (exciton localization and hopping) typical of ternary InGaN alloy with highly suppressed nonradiative recombination.