Ultrasonic-Assisted Extraction of Toxic Acidic Components from Acidic Oil Using 1,8-Diazobicyclo[5.4.0]undec-7-ene-Based Ionic Liquids

Shah, Syed Nasir; Shah, Mansoor Ul Hassan; Mutalib, M.I. Abdul; Lethesh, Kallidanthiyil Chellappan; Lévêque, Jean–Marc; Ullah, Nehar; Suleman, Humbul

doi:10.1021/acsomega.2c02514

Cited by 2 publications

(1 citation statement)

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“…ILs are made up of cation-anion pairs, and the pairing allows tuning of their physicochemical properties to the application. ( Giernoth, 2010 ; Nasir Shah et al, 2022 ). A systematic study of both physicochemical and transport properties of commercially available ILs helps researchers select suitable ILs for their applications, thereby speeding up product development and improving process economics.…”

Section: Introductionmentioning

confidence: 99%

Ionic liquid electrolyte selection for high voltage supercapacitors in high-temperature applications

Bahaa,

Alhammadi,

Lethesh

et al. 2024

Front. Chem.

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Systematic analyses of electrolyte physicochemical properties are important to screen ionic liquids (ILs) and understand the electrochemical performance of supercapacitor electrolytes. This study harmonizes the evaluation of electrochemical performance and transport properties of eight shortlisted ILs from 22 commercially available hydrophobic ILs toward achieving a ≥ 5 V supercapacitor capable of high-temperature operation (up to 353.15 K). The eight ILs are N-Propyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide ([Pyr 1, 3] [TFSI], N-Pentyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide ([Pyr 1, 5] [TFSI]), N-Propyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide ([Pyr 1, 3] [FSI]), 1-Methyl-1-(2-methoxyethyl)pyrrolidinium Bis(trifluoromethanesulfonyl)imide ([Pyr 1, 102] [TFSI]), 1-Methyl-1-propylpiperidinium bis(trifluoromethanesulfonyl)imide ([Pip 1, 3] [TFSI]), 1-Methyl-1-propylpiperidinium bis(fluorosulfonyl)imide ([Pip 1, 3] [FSI]), N-Trimethyl-N-propylammonium bis(trifluoromethanesulfonyl)imide ([N 111, 3] [TFSI]), N-Trimethyl-N-hexylammonium bis(trifluoromethanesulfonyl)imide ([N 111, 6] [TFSI]). The density, viscosity, and ionic conductivity of the eight ILs were measured between 278.15 and 373.15 K to confirm the effects of temperature and ion structure before electrochemical characterization. The [FSI]-based ILs ([Pip 1, 3] [FSI] and [Pyr 1, 3] [FSI]) showed lower densities and viscosities compared to other ILs among the eight based on [TFSI]. Consequently, the highest conductivity was obtained for [Pyr 1, 3] [FSI]. Cyclic voltammetry and impedance spectroscopy was performed on supercapacitors assembled with the eight ILs as electrolytes between 298.15–353.15 K. Conclusion from the two-electrode supercapacitors using multi-walled carbon nanotubes showed the 6 most-applicable ILs towards the targeted ≥ 5 V SC at high temperature are [Pip 1, 3] [TFSI] (5.4 V), [Pip 1, 3] [FSI] (5 V), [N 111, 3] [TFSI] (5.1 V), [N 111, 6] [TFSI] (5.2 V), [Pyr 1, 102] [TFSI] (5.2 V), and [Pyr 1, 5] [TFSI] (5.2 V).

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Section: Introductionmentioning

confidence: 99%