We found that 90 • domain walls are absorptive to oxygen vacancies and the absorbing degree was related with the morphology of 90 • domain walls: curved 90 • domain walls are more absorptive to oxygen vacancies compared with straight 90 • domain walls. Therefore, in ferroelectric materials with curved 90 • domain walls, the density of oxygen vacancies diffusing to and subsequently pinning the 180 • domain walls is greatly suppressed, resulting in their excellent fatigue resistance.