Hybrid micro/nanostructures and light-absorbing pigment of melanin are two key factors for the excellent antireflective properties of the butterfly wings of Ornithoptera goliath. In this work, femtosecond laser ablation of metals in an organic solvent (FLAMOS) was used to generate hybird micro/ nanostructured cross-linked ultrahigh/low spatial frequency laserinduced periodic surface structures (UHSFLs/LSFLs), which well mimic the antireflective architecture of Ornithoptera goliath. The simultaneously deposited carbon or newly formed transition metal carbide (TMC) plays the same role of light-absorbing pigment of melanin on Ornithoptera goliath. A total of 13 transition metals and one transition-metal alloy