Ultrafast coherent THz lattice dynamics coupled to spins in a van der Waals antiferromagnetic flake

Abstract

A coherent THz optical lattice mode is triggered by femtosecond laser pulses in the antiferromagnetic van der Waals semiconductor FePS 3 . The 380 nm thick exfoliated flake was placed on a substrate and laser-driven lattice and spin dynamics were investigated as a function of the excitation photon energy and sample temperature.The pump-probe spectroscopic measurements reveal that the photo-induced phonon is generated by a displacive mechanism. The amplitude of the phononic signal decreases as the sample is heated up to the Néel temperature and vanishes as the phase transition to the paramagnetic phase occurs. This evidence confirms that the excited lattice mode is intimately connected to the long-range magnetic order. Therefore our work discloses a pathway towards a femtosecond coherent manipulation of the magneto-crystalline anisotropy in a van der Waals antiferromagnet. In fact, it is reported that by applying a magnetic field the induced phonon mode hybridizes via the Kittel-mechanism with zone-centre magnons.

Magnetoelectrics and multiferroics: theory, synthesis, characterisation, preliminary results and perspectives for all-optical manipulations

“…This method is particularly effective when competing exchange interactions, for example between ferro-and antiferromagnetic (AFM) contributions, can be tweaked so that a transition between different orders can be achieved. Accordingly, experiments have shown that exchange interactions and anisotropy can be modulated by optically driven phonons which lead to spin reorientation transitions and coherent spin dynamics [96][97][98][99][100][101]. In those studies, both infrared-active and Raman-active phonons have been driven through laser pulses in the terahertz and near visible light spectral ranges.…”