1992
DOI: 10.1149/1.2069171
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Ultra Shallow Junction Formation Using Diffusion from Silicides: II . Diffusion in Silicides and Evaporation

Abstract: The phenomena associated with dopant redistribution in TiSi2, CoSi2, NiSi, Pd2Si, and PtSi, as would be used in a silicide-As-diffusion-source process, were examined. Segregation of dopant (B) into a surface layer, evaporation of dopant, and slow, grain-boundary diffusion, were found to occur in annealed, implanted silicides. For CoSi2, 1.6 • 1014 boron atoms/cm 2 were found to segregate to the silicide surface, independent of the initial implant dose, possibly as B203. The evaporation coefficient was found to… Show more

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Cited by 28 publications
(9 citation statements)
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“…For SADS, the dopant will diffuse towards and segregate at the interface of NiSi/Si to modulate the SBHs during the drive-in annealing. Because of the low diffusion capability of boron in nickel silicide [12], not so much boron will reach the interface after the drive-in annealing process, which causes the tiny increase of SBHs in Fig.2 Fig.3 The modulation of SBHs with different implantation dosage.…”
Section: Resultsmentioning
confidence: 99%
“…For SADS, the dopant will diffuse towards and segregate at the interface of NiSi/Si to modulate the SBHs during the drive-in annealing. Because of the low diffusion capability of boron in nickel silicide [12], not so much boron will reach the interface after the drive-in annealing process, which causes the tiny increase of SBHs in Fig.2 Fig.3 The modulation of SBHs with different implantation dosage.…”
Section: Resultsmentioning
confidence: 99%
“…This is consistent with other reports that much more arsenic is evaporated compared with boron in CoSi 2 with annealing temperature, which can be explained by the fact that the activation energy for boron and arsenic evaporation from CoSi 2 is 4.4 and 2.0 eV, respectively. 15 Considering that the concentration of the p-well and n-well is 1 ϫ 10 17 cm Ϫ3 , the depths of the n ϩ and p ϩ junctions annealed at 900ЊC are about 100 and 130 nm from the silicide/silicon interface, respectively. From the Co depth profiles in Fig.…”
Section: Resultsmentioning
confidence: 99%
“…Silicides on Si substrates can agglomerate, resulting in rough and discontinuous films during annealing. 15 Agglomeration is driven by the reduction of surface and interface energies of the silicide and starts with grain boundary grooving at the intersection of silicide grain boundaries. 16,17 During agglomeration, metal atoms diffuse away from the silicide grain boundaries along with diffusion of Si to the silicide grain boundaries, especially in near noble metal silicides such as NiSi and CoSi 2 , where the metals have a high diffusivity compared to Si.…”
Section: Resultsmentioning
confidence: 99%
“…Clearly, the samples annealed with laser show a higher doping concentration at the silicide/silicon interface compared with the reference sample. Boron atoms redistribute and segregate to the silicide surface and silicide/silicon interface by diffusion in nickel silicide grain boundaries during silicidation [6]. The higher segregation doping in ELA sample is attributed to the difference in boron out-diffusion rate between the substitutional boron for the annealed sample and the interstitial boron for the asimplanted sample [7].…”
Section: Diodes and Materials Characterizationmentioning
confidence: 99%