The negative bias temperature instability (NBTI) reliability of sub-1-nanometer equivalent oxide thickness (EOT) ZrO 2 and HfO 2 dielectrics with metal gate is investigated. The threshold voltage shift ( V TH ) at identical NBTI overdrive stress conditions is observed to be lower in ZrO 2 than in HfO 2 field-effect transistors. Ring oscillator charge pumping is applied to determine interface trap generation ( N it ) in the sub-1-nanometer EOT devices, with ZrO 2 devices showing about one order of magnitude lower N it than HfO 2 device. However, the N it contribution to the total V TH is very limited in sub-1-nanometer EOT devices, as the recoverable component from the pre-existing bulk defects dominates the whole NBTI degradation. Pulsed Id-Vg technique is applied to analyze the pre-existing bulk defects in those sub-1-nanometer EOT devices, and lower pre-existing bulk defect density is shown in ZrO 2 , which decisively reduces NBTI in ZrO 2 gate dielectric.Index Terms-Dielectric reliability, negative bias temperature instability (NBTI), oxide defect, thin equivalent oxide thickness (EOT).