Ueber die Schwefelverbindungen des Molybdäns;

Abstract

Die von B e r z e 1 i u B *) in seinen umfangreichen Arbeih ,Ueber die SchwefelsabtP bsschriubenen ATSB&-und Moly&-d~X:tcechwefehades bilden die ersten Repribentanten jeoer p f s e n Anzabl von Verbindungen, welche ~t e r dem Nsaea ~&2fcealesu msammengefafst werden. B e r i e 1 i u 8 verfolgte bei jenen Arbeiten jedoch, wie er selbst spiiter bervorhebt *), vor Allenr den Zwecli, .das Vorhandensein h e r grofmn €Upsee von Saleen t u erweisen, welche, mit Schwefel ab Amphid, den bekannten Sauerstoffsaben voWndig analog eindq. Br beabsichtigte deshalb nur den allgememen Charakter dieser Sake zu hestimmen und unterwarf die ungefdhr iN von ihm dargestellten Sulfoverbindungen, wie er sagt (a. a. 0.h nur einer aufserst fluchtigen Untersuchq. *) B w d n Wetwehaps ahadsmiens h.ndl;llgu 1 9 . 1 , 80 und nebs, 282; Pogg. Ann. 6n, 449.-) ArsberPtkae 18t6, 193.

Electrodeposition of amorphous molybdenum sulfide thin film for electrochemical hydrogen evolution reaction

“…Some researchers used the commodity ((NH) 2 MoS 4 ) [13, 21, 25–27], however, the commodity ((NH) 2 MoS 4 ) is highly expensive, therefore, some researchers synthesize the ((NH) 2 MoS 4 ) solution [28–30]. The methods for preparing of ammonium tetrathiomolybdate ((NH 4 ) 2 (MoS 4 )) species are almost identical to Krüss [29], and the methods was improved by John W. McDonald’s group [30] for the preparation of (NH 4 ) 2 (MoO 2 S 2 ), (NH 4 ) 2 (MoOS 3 ) and (NH 4 ) 2 (MoS 4 ). The synthesis involves the exhaustive treatment by H 2 S gas of molybdate solution in concentrated NH 4 OH.…”

Photogalvanic generation of dihydrogen by water splitting using MoS 4 2− as catalyst

“…(NH4) z MoS4 was synthesized following the method earlier reported (Kruss 1884) and characterized by analytical and spectroscopic data (Diemann and Mueller 1973). The IR spectra were measured as KBr pellets using a spectrophotometer (Perkin Elmer 597).…”

Ni(Co)-Mo-W sulphide unsupported HDS catalysts by ex situ decomposition of alkylthiomolybdotungstates

“…The synthesis of ammonium thiomolybdate (ATM) and ammonium thiotungstate (ATT) has been reported since long time ago [32][33][34], however we have followed a method used by Alonso et al [35].…”