1960
DOI: 10.1007/bfb0119066
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Überblick über einige physikalisch-chemische Eigenschaften der AIIIBv-Verbindungen unter besonderer Berücksichtigung der Zustandsdiagramme

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Cited by 3 publications
(3 citation statements)
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“…In our own systematic investigations of the vapor deposition of elementary boron (5) however, we have shown that it is impossible to prepare this so-called "I-tetragonal boron" B4sBz in a pure form and that it can therefore no longer be considered a true polymorph of elementary boron. We suggest that the formation of this boron "modification" in the reported experiments (2)(3)(4) was induced in such a way that the deposited boron picked up some carbon from the substrate and reacted on the surface. This resulted in the nucleation and growth of crystals, which actually were tetragonal boron carbide and not pure tetragonal boron.…”
Section: Discussionmentioning
confidence: 70%
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“…In our own systematic investigations of the vapor deposition of elementary boron (5) however, we have shown that it is impossible to prepare this so-called "I-tetragonal boron" B4sBz in a pure form and that it can therefore no longer be considered a true polymorph of elementary boron. We suggest that the formation of this boron "modification" in the reported experiments (2)(3)(4) was induced in such a way that the deposited boron picked up some carbon from the substrate and reacted on the surface. This resulted in the nucleation and growth of crystals, which actually were tetragonal boron carbide and not pure tetragonal boron.…”
Section: Discussionmentioning
confidence: 70%
“…(9), or reaction [1] only (Ref. 10), was resolved by Stevenson and Yost (11), who calculated the equilibrium constant Kp' of reaction [2] from spectroscopic data and showed that reaction [2] does indeed not contribute in a measurable way to the vapor pressure at T < 1500~ Utilizing the data of Ref. (10), a fairly constant value of ~H~ for reaction [1] was obtained from K r at various temperatures, while the same test of consistency fails for the data of Ref.…”
Section: K;mentioning
confidence: 99%
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