1974
DOI: 10.1002/jlac.197419740907
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Über zweistufige Redoxsysteme, XV1) Synthesen vinyloger Bibenzimidazole, Bibenzoxazole und Bibenzothiazole sowie ihrer Aza‐Derivate

Abstract: Die Redoxsysteme N1–3, O1–2 und S1–3 sowie einige Diaza‐ und Tetraazaderivate werden auf verschiedenen Wegen synthetisiert. Je nach System sind die reduzierten oder/und die oxidierten Formen zugänglich.

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Cited by 17 publications
(6 citation statements)
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“…For the synthesis of 5, a potential starting material has been reported in compound 8, which may be susceptible to double deprotonation, furnishing 5. [26] Given the availability of these possible starting reagents, we are currently targeting the synthetic isolation and applications of 5 and 6 as strong, bifunctional carbon-based ligands.…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…For the synthesis of 5, a potential starting material has been reported in compound 8, which may be susceptible to double deprotonation, furnishing 5. [26] Given the availability of these possible starting reagents, we are currently targeting the synthetic isolation and applications of 5 and 6 as strong, bifunctional carbon-based ligands.…”
Section: Methodsmentioning
confidence: 99%
“…[26] Given the availability of these possible starting reagents, we are currently targeting the synthetic isolation and applications of 5 and 6 as strong, bifunctional carbon-based ligands.…”
Section: Angewandte Chemiementioning
confidence: 99%
“…For the synthesis of 5 , a potential starting material has been reported in compound 8 , which may be susceptible to double deprotonation, furnishing 5 26…”
Section: Calculated (Mp2/tzvp//b3lyp/tzvp) First and Second Proton Afmentioning
confidence: 99%
“…Compound 1 had been previously reportedi n1974 by Hünig and co-workers as part of aw ider examination of vinylbenzimidazoles, with some redox chemistry described, but the compound was not characterised. [16] With the above ideas in mind, we began to investigate experimentally andt heoretically if 1 exhibits properties that agree with the notion of ab ifunctional NHO. In this report we show that while the reactivityd oes not follow NHOs,t he exocyclic C=Cb ond in the compound is highly unusual in that it is extremely weak.…”
Section: Introductionmentioning
confidence: 99%