Über die Legierungen des Magnesiums mit Zinn und Blei

Thermodynamic modeling of the Mg–Sn–Zn ternary system

“…The calculated liquidus of bct(Sn) phase and the solidus of hcp(Mg) phase are also consistent with the experimental data [25][26][27][28][29][30][31][32][33][34][35]. The calculated temperatures and compositions of invariant reactions are compared with the experimental data [26][27][28][29][30][31][32]34,35,45,46] and the assessed values by Fries and Lukas [23] in Table 2. As can be seen, the calculated results including liquidus, solidus and temperatures and compositions of invariant reactions are in good agreement with most of the experimental data and the assessed results [23].…”

“…There are some slight discrepancies for the measured liquidus of the hcp(Mg) phase and intermetallic compound Mg2Sn, while the reported that of the bct(Sn) phase are in good agreement with each other. After analyzed carefully these experimental data [25][26][27][28][29][30][31][32][33], Nayeb-Hashemi and Clark [22] pointed out that the experimental results of Hume-Rothery [28], Raynor [29] and Steiner et al [30] are much more reliable than others. This conclusion was accepted in the present work.…”

“…4. Calculated phase diagram of the Mg-Sn binary system compared with the experimental data [26][27][28][29][30][31][32][33][34][35]47] in the present work. measuring the effect of Mg on the freezing point of molten Sn.…”

“…The Mg-Sn binary system was investigated by many researchers [25][26][27][28][29][30][31][32][33][34][35][36]. Heycock and Neville [25] determined firstly the liquids of the bct(Sn) phase through Fig.…”

“…measuring the effect of Mg on the freezing point of molten Sn. Afterwards, the liquidus was determined by Grube [26], Kurnakow and Stepanow [27], Hume-Rothery [28], Raynor [29] and Steiner et al [30] using thermal analysis as well as by Nayak and Oelsen [31,32] using calorimetry. Also, Ellmer et al [33] reported the liquidus in the Sn-rich side.…”